Study of localized corrosion of 304 stainless steel under chloride solution droplets using the wire beam electrode

被引:76
作者
Wang, Yanhua [1 ]
Wang, Wei [1 ]
Liu, Yuanyuan [1 ]
Zhong, Lian [1 ]
Wang, Jia [1 ,2 ]
机构
[1] Ocean Univ China, Coll Chem & Chem Engn, Minist Educ, Key Lab Marine Chem Theory & Technol, Qingdao 266100, Peoples R China
[2] State Key Lab Corros & Protect, Shenyang 110016, Peoples R China
基金
中国国家自然科学基金;
关键词
Stainless steel; Atmospheric corrosion; 3-PHASE BOUNDARY ZONE; PITTING CORROSION; ATMOSPHERIC CORROSION; STAINLESS-STEEL; INITIAL-STAGE; BEHAVIOR;
D O I
10.1016/j.corsci.2011.05.051
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Localized corrosion of 304 stainless steel under droplets of 1 M sodium chloride solution was investigated by the wire beam electrode (WBE) method. It was found that the current distributions were heterogeneous with isolated anodic current peaks mostly located near the edge of the droplet. During the corrosion process, the stainless steel WBE exhibited the stochastic characteristics with the disappearance of some anodic sites. In addition, stainless steel suffered more serious localized corrosion with the increase of the droplet size. The increase of the cathodic area and the three-phase boundary (TPB) length was believed to be the reason. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:2963 / 2968
页数:6
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