Tricyclohexylphosphine derivatives of bis(2,6-difluorophenoxide)cadmium: A solution and solid-state NMR study

被引：6
作者：
Darensbourg, DJ [1 ]
Wildeson, JR [1 ]
Yarbrough, JC [1 ]
Taylor, RE [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
来源：
INORGANIC CHEMISTRY | 2001年 / 40卷 / 14期
关键词：
D O I：
10.1021/ic010104q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of Cd(O-2,6-F2C6H3)(2)(PCy3)(2) has been achieved by the reaction of Cd[N(SiMe3)(2)](2) and 2,6-difluorophenol in THF in the presence of 2 equiv of tricyclohexylphosphine, and its distorted tetrahedral structure has been established by X-ray crystallography. Comparison of the solution and solid-state Cd-113 NMR spectra of this derivative suggest that a facile solution equilibrium exists between it and its dimeric monophosphine analogue and free PCy3. At ambient temperature, the equilibrium lies strongly in favor of the dimeric complexes, whereas at -80 degreesC, the monomeric complex is dominant. <Graphics>
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页码：3639 / 3642
页数：4
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