Oxidation in Iron-Copper and Iron-Phosphorous Binary Alloys: Relating Alloying and Metal-Oxide Crystallography with Oxidation Resistance

被引：5
|
作者：
Mehtani, H. K. [1 ,2 ]
Khan, M., I [1 ]
Raut, P. [3 ]
Parida, S. [1 ]
Prasad, M. J. N., V [1 ]
Fullwood, D. [4 ]
Doherty, R. D. [1 ,5 ]
Samajdar, I [1 ]
机构：
[1] Indian Inst Technol, Dept Met Engn & Mat Sci, Mumbai 400076, Maharashtra, India
[2] TIET, Dept Mech Engn, Patiala 147004, Punjab, India
[3] Indian Inst Technol, Dept Mech Engn, Mumbai 400076, Maharashtra, India
[4] Brigham Young Univ, Dept Mech Engn Dept, Provo, UT 84602 USA
[5] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
来源：
OXIDATION OF METALS | 2022年 / 97卷 / 3-4期
关键词：
Iron; Phosphorous; Copper; Oxidation; Microstructure; Texture; HIGH-TEMPERATURE OXIDATION; DEFINING ROLE; MECHANICAL-PROPERTIES; BEHAVIOR; STRESSES; STRAIN; MICROSTRUCTURE; ORIENTATION; DIFFUSION; CORROSION;
D O I：
10.1007/s11085-022-10099-2
中图分类号：
TF [冶金工业];
学科分类号：
0806 ;
摘要：
This study showed significant improvements in resistance to oxidation of iron (Fe) with copper (Cu: 0-3.4 weight %) or phosphorous (P: 0-0.12 weight %) alloying. All these binary alloys had bcc ferrite structure and maintained (i) a homo-epitaxy with the oxide (magnetite-Fe3O4) phase below 843 K and (ii) a pseudo-epitaxy with pro-eutectoid magnetite > 843 K. The epitaxial growth, in particular, introduced dislocations, residual stress, and misfit strain in the 'thin' (a few hundred nanometer) oxide film. These were stronger for oxides on near ND|| Fe grains, but reduced noticeably with an increase in Cu or P content. The reduced epitaxial strain, residual stress and associated dislocations, appeared to correlate with the improved oxidation resistance-relating alloying and metal-oxide crystallography to oxidation resistance in dilute Fe-Cu and Fe-P binary alloys.
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收藏
页码：417 / 440
页数：24
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