Synthesis, Structural and Optical Properties of Er and V Codoping ZnO Nanoparticles

被引:7
作者
El Ghoul, J. [1 ,2 ]
Al-Harbi, F. F. [3 ]
机构
[1] Gabes Univ, Fac Sci Gabes, Lab Phys Mat & Nanomat Appl Environm LaPhyMNE, Gabes 6072, Tunisia
[2] Imam Mohammad Ibn Saud Univ IMSIU, Coll Sci, Dept Phys, Riyadh 11623, Saudi Arabia
[3] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Phys, Riyadh, Saudi Arabia
关键词
ZnO; Rare earth doping; Nanoparticles; Structural properties; Photoluminescence; ROOM-TEMPERATURE FERROMAGNETISM; MAGNETIC-PROPERTIES; CO; MN; NANOSTRUCTURES; LUMINESCENCE; FILMS;
D O I
10.1007/s10904-020-01678-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Here we are reporting sol-gel synthesis diluted magnetic (Er, V)-co-doped ZnO nanocrystals as a dilute semiconductor. The structural and morphological properties were studied using some techniques such as X-rays diffraction (XRD) and transmission electron microscopy (TEM). The optical properties were characterized by Spectrophotometer UV-Visible-IR and photoluminescence (PL). The structural properties showed the appearance of wurtzite structure with a crystallite size around 45 nm and a secondary phase has been detected, attributed to Erbium complex. Raman measurements show that the good quality of the crystals is also maintained after doping, which is confirmed by the coexistence of the polar and non-polar modes E(1)and E-2, respectively. The increase in the doping concentration of Er caused a decrease in band gap energy. PL shows the appearance of some defects between the valence and conduction band of ZnO linked to doping with Er.
引用
收藏
页码:272 / 278
页数:7
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