Conversion of Mono- and Disaccharides to Ethyl Levulinate and Ethyl Pyranoside with Sulfonic Acid-Functionalized Ionic Liquids

被引：160

作者：

Saravanamurugan, Shunmugavel ^{[1
]}

Van Buu, Olivier Nguyen ^{[1
]}

Riisager, Anders ^{[1
]}

机构：

[1] Tech Univ Denmark, Ctr Catalysis & Sustainable Chem, Dept Chem, DK-2800 Lyngby, Denmark

来源：

CHEMSUSCHEM | 2011年 / 4卷 / 06期

关键词：

carbohydrates; dehydration; ethyl levulinate; ionic liquids; sulfonic acid; PHASE SILP CATALYSIS; ORGANIC-ACIDS; LACTIC-ACID; BIOMASS; DEHYDRATION; FRUCTOSE; FUELS; HYDROFORMYLATION; HYDROGEN; GLUCOSE;

D O I：

10.1002/cssc.201100137

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Value-added chemicals from sugars: Sulfonic acid-functionalized ionic liquids are attractive and promising catalyst for the conversion of sugars to ethyl levulinate and ethyl-D-glucopyranoside in ethanol. These task-specific ionic liquids can be recovered and reused in at least three cycles in the conversion of fructose to ethyl levulinate without any loss of activity. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：723 / 726

页数：4

共 58 条

[1] GAMMA, GAMMA-BIS-(PARA-HYDROXYPHENYL)-VALERIC ACID [J].

BADER, AR ;

KONTOWICZ, AD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (17) :4465-4466

[2] 1-Methylimidazolium Chlorosulfate ([HMIm]SO3Cl): A Novel Ionic Liquid with Dual Bronsted-Lewis Acidity [J].

Bao, Quanxi ;

Qiao, Kun ;

Tomida, Daisuke ;

Yokoyama, Chiaki .

CHEMISTRY LETTERS, 2010, 39 (07) :728-729

[3] DEHYDRATION REACTIONS OF FRUCTOSE IN NON-AQUEOUS MEDIA [J].

BROWN, DW ;

FLOYD, AJ ;

KINSMAN, RG ;

ROSHANALI, Y .

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 1982, 32 (10) :920-924

[4] Selective Conversion of Fructose to 5-Hydroxymethylfurfural Catalyzed by Tungsten Salts at Low Temperatures [J].

Chan, Jin Young Gerentt ;

Zhang, Yugen .

CHEMSUSCHEM, 2009, 2 (08) :731-734

[5]

Chheda J.N., 2007, Angew. Chem, V119, P7298

[6] Liquid-phase catalytic processing of biomass-derived oxygenated hydrocarbons to fuels and chemicals [J].

Chheda, Juben N. ;

Huber, George W. ;

Dumesic, James A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (38) :7164-7183

[7] DERIVATIVES OF GAMMA-VALEROLACTONE, 1,4-PENTANEDIOL AND 1,4-DI-(BETA-CYANOETHOXY)-PENTANE [J].

CHRISTIAN, RV ;

BROWN, HD ;

HIXON, RM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1947, 69 (08) :1961-1963

[8] Novel bronsted acidic ionic liquids and their use as dual solvent-catalysts [J].

Cole, AC ;

Jensen, JL ;

Ntai, I ;

Tran, KLT ;

Weaver, KJ ;

Forbes, DC ;

Davis, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (21) :5962-5963

[9] Preparation of environmentally friendly alkylglucoside surfactants using zeolites as catalysts [J].

Corma, A ;

Iborra, S ;

Miquel, S ;

Primo, J .

JOURNAL OF CATALYSIS, 1996, 161 (02) :713-719

[10] Chemical routes for the transformation of biomass into chemicals [J].

Corma, Avelino ;

Iborra, Sara ;

Velty, Alexandra .

CHEMICAL REVIEWS, 2007, 107 (06) :2411-2502

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