A rational assembly of a series of exchange coupled linear heterotrinuclear complexes of the type MAMBMC as exemplified by FeIIICuIINiII, FeIIINiIICuII and CoIIICuIINiII

被引：50

作者：

Verani, CN ^{[1
]}

Weyhermuller, T ^{[1
]}

Rentschler, E ^{[1
]}

Bill, E ^{[1
]}

Chaudhuri, P ^{[1
]}

机构：

[1] Max Planck Inst Strahlenchem, D-54513 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 22期

关键词：

D O I：

10.1039/a806575f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A general approach for the rational synthesis of linear trinuclear complexes containing three different metals MAMBMC is described and a member of the series, (FeCuII)-Cu-III-Ni-II, has been characterized by X-ray crystallography and magnetic susceptibility measurements.

引用

页码：2475 / 2476

页数：2

共 20 条

[1] Crystal structure and spin-doublet electron spin resonance of a magnetically coupled di(mu-phenoxo)-copper(II)nickel(II) complex [J].

Aono, T ;

Wada, H ;

Aratake, Y ;

Matsumoto, N ;

Okawa, H ;

Matsuda, Y .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (01) :25-29

[2] EXCHANGE COUPLING IN HOMODINUCLEAR HETERODINUCLEAR COMPLEXES CUIIM [M = CR(III), MN(III), MN(II), FE(III), CO(III), CO(II), NI(II), CU(II), ZN(II)] - SYNTHESIS, STRUCTURES, AND SPECTROSCOPIC PROPERTIES [J].

BIRKELBACH, F ;

WINTER, M ;

FLORKE, U ;

HAUPT, HJ ;

BUTZLAFF, C ;

LENGEN, M ;

BILL, E ;

TRAUTWEIN, AX ;

WIEGHARDT, K ;

CHAUDHURI, P .

INORGANIC CHEMISTRY, 1994, 33 (18) :3990-4001

[3] Competing exchange interactions and ground-state variability: Linear homo- and heterotrinuclear manganese(III, IV) complexes with tris(dimethylglyoximato)metalate(II) tetraanions as bridging ligands [J].

Birkelbach, F ;

Florke, U ;

Haupt, HJ ;

Butzlaff, C ;

Trautwein, AX ;

Wieghardt, K ;

Chaudhuri, P .

INORGANIC CHEMISTRY, 1998, 37 (08) :2000-2008

[4] Encapsulation by a chromium(III)-containing bicyclic ligand cage.: Synthesis, structures, and physical properties of heterometal complexes CrIII MCrIII [M=(H+)2, Li(I), Mg(II), Cu(II), Ni(II), Ni(IV), Co(III), Fe(II), Fe(III), Mn(II)] [J].

Burdinski, D ;

Birkelbach, F ;

Weyhermuller, T ;

Florke, U ;

Haupt, HT ;

Lengen, M ;

Trautwein, AX ;

Bill, E ;

Wieghardt, K ;

Chaudhuri, P .

INORGANIC CHEMISTRY, 1998, 37 (05) :1009-1020

[5] SELF-ASSEMBLY OF A NOVEL 14-MEMBERED METALLAMACROBICYCLE CONTAINING 2 CHROMIUM(III) IONS AS PART OF THE RING SKELETON [J].

BURDINSKI, D ;

BIRKELBACH, F ;

GERDAN, M ;

TRAUTWEIN, AX ;

WIEGHARDT, K ;

CHAUDHURI, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (09) :963-964

[6] SYNTHESIS, ELECTROCHEMISTRY, AND MAGNETIC AND SPECTROSCOPIC PROPERTIES OF AN EXCHANGE-COUPLED FEIIINIIIFEIII COMPLEX - CRYSTAL-STRUCTURE OF [L2FE2(DMG)3NI](PF6)2.0.5CH3OH (L = 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE - DMG = DIMETHYLGLYOXIMATE(2-)) [J].

CHAUDHURI, P ;

WINTER, M ;

DELLAVEDOVA, BPC ;

FLEISCHHAUER, P ;

HAASE, W ;

FLORKE, U ;

HAUPT, HJ .

INORGANIC CHEMISTRY, 1991, 30 (25) :4777-4783

[7] SYNTHESIS, STRUCTURE AND MAGNETISM OF A TETRANUCLEAR FE(III) COMPLEX CONTAINING AN [FE4(MU(3)-O)2]8+ CORE [J].

CHAUDHURI, P ;

WINTER, M ;

FLEISCHHAUER, P ;

HAASE, W ;

FLORKE, U ;

HAUPT, HJ .

INORGANICA CHIMICA ACTA, 1993, 212 (1-2) :241-249

[8] A NOVEL SERIES OF HETEROTRINUCLEAR COMPLEXES WITH A TRIS(DIMETHYLGLYOXIMATO)METAL(II) ANION AS BRIDGING LIGAND - STRUCTURE OF THE FEIIICUIIFEIII COMPLEX WITH S = 9/2 GROUND-STATE [J].

CHAUDHURI, P ;

WINTER, M ;

FLEISCHHAUER, P ;

HAASE, W ;

FLORKE, U ;

HAUPT, HJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (23) :1728-1730

[9] A NOVEL TETRANUCLEAR [CRIII2MNIII2(MU(3)-O)2]8+ CORE WITH AN S(T)=0 SPIN GROUND-STATE [J].

CHAUDHURI, P ;

BIRKELBACH, F ;

WINTER, M ;

STAEMMLER, V ;

FLEISCHHAUER, P ;

HAASE, W ;

FLORKE, U ;

HAUPT, HJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (15) :2313-2319

[10]

GUTLICH P, 1978, MOSSBAUER SPECTROSCO

← 1 2 →