POLYPROPYLENE/CLAY NANOCOMPOSITES. SYNTHESIS AND CHARACTERIZATION

被引:11
|
作者
Perez, Monica A. [1 ]
Rivas, Bernabe L. [1 ]
Rodriguez, Saddys M. [2 ]
Maldonado, Alvaro [2 ]
Venegas, Carola [2 ]
机构
[1] Univ Concepcion, Fac Ciencias Quim, Dept Polimeros, Concepcion, Chile
[2] Univ Concepcion, Unidad Desarrollo Tecnol, Concepcion, Chile
关键词
Nanocomposites; polypropylene; clays; compatiblizer agent; LAYERED SILICATE NANOCOMPOSITES; PROCESSING CONDITIONS; MECHANICAL-PROPERTIES; POLY(PROPYLENE); INTERCALATION; POLYOLEFINS; POLYMERS; NANOCLAY; BEHAVIOR; HYBRID;
D O I
10.4067/S0717-97072010000400006
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polypropylene nanocomposites were synthesized by using the method of mixing in the molten state. Nanocomposites were obtained in twin-screw co-rotating extruders and the nanocomposites were prepared with percentage of nanoclay (C(2)) from 5 wt-%, with and without compatibilizer agent (PP-g-MA). The thermal (DSC, TGA), morphology (XRD, TEM), and dynamical mechanical (DMA) properties of the nanocomposites were characterized. All nanocomposites prepared are in intercalated state as corroborated by XRD and TEM. The Tm and Xc were not affected by the presence of clay, PP-g-MA, or processing support. The incorporation of clay and compatibilizer agent increases the thermal stability and heat deflection temperature (HDT).
引用
收藏
页码:440 / 444
页数:5
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