On single-file and less dense processes

被引:22
作者
Flomenbom, O. [1 ]
Taloni, A. [2 ,3 ]
机构
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
[2] MIT, Dept Phys, Cambridge, MA 02139 USA
[3] Acad Sinica, Inst Phys, Taipei 11529, Taiwan
关键词
D O I
10.1209/0295-5075/83/20004
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The diffusion process of N hard rods in a 1D interval of length L(->infinity) is studied using scaling arguments and an asymptotic analysis of the exact N-particle probability density function (PDF). In the class of such systems, the universal scaling law of the tagged particle's mean absolute displacement reads, <vertical bar r vertical bar >approximate to <vertical bar r vertical bar > free/n(mu), where <vertical bar r vertical bar > free is the result for a free particle in the studied system and n is the number of particles in the covered length. The exponent mu is given by, mu=1/(1+alpha), where alpha is associated with the particles' density law of the system, rho approximate to rho 0L(-alpha), 0 <=alpha <= 1. The scaling law for <vertical bar r vertical bar > leads to, <vertical bar r vertical bar >approximate to rho 0((alpha-1)/2)(<vertical bar r vertical bar > free)((1+alpha)/2), an equation that predicts a smooth interpolation between single-file diffusion and free-particle diffusion depending on the particles' density law, and holds for any underlying dynamics. In particular, < r(2)>approximate to t(1+alpha/2) for normal diffusion, with a Gaussian PDF in space for any value of alpha (deduced by a complementary analysis), and, < r2 >approximate to t(beta(1+alpha)/2) , for anomalous diffusion in which the system's particles all have the same power-law waiting time PDF for individual events, psi approximate to t(-1-beta), 0 <beta < 1. Our analysis shows that the scaling < r(2)>approximate to t(1/2) in a "standard" single file is a direct result of the fixed particles' density condition imposed on the system, alpha=0. Copyright (C) EPLA, 2008.
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页数:6
相关论文
共 41 条
[1]  
Alberts B., 1994, MOL BIOL CELL
[2]   DIFFUSION OF LABELED PARTICLES ON ONE-DIMENSIONAL CHAINS [J].
ALEXANDER, S ;
PINCUS, P .
PHYSICAL REVIEW B, 1978, 18 (04) :2011-2012
[3]   Single-file diffusion with random diffusion constants [J].
Aslangul, C .
JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 2000, 33 (05) :851-862
[4]   Single-file diffusion of subdiffusive particles [J].
Bandyopadhyay, T. .
EPL, 2008, 81 (01)
[5]   The Bethe ansatz after 75 years [J].
Batchelor, Murray T. .
PHYSICS TODAY, 2007, 60 (01) :36-40
[6]   Metal theory [J].
Bethe, H. .
ZEITSCHRIFT FUR PHYSIK, 1931, 71 (3-4) :205-226
[7]   Single file diffusion enhancement in a fluctuating modulated quasi-1D channel [J].
Coupier, G. ;
Saint Jean, M. ;
Guthmann, C. .
EPL, 2007, 77 (06)
[8]   REPTATION OF A POLYMER CHAIN IN PRESENCE OF FIXED OBSTACLES [J].
DEGENNES, PG .
JOURNAL OF CHEMICAL PHYSICS, 1971, 55 (02) :572-+
[9]   Dynamical behavior of one-dimensional water molecule chains in zeolites: Nanosecond time-scale molecular dynamics simulations of bikitaite [J].
Demontis, P ;
Stara, G ;
Suffritti, GB .
JOURNAL OF CHEMICAL PHYSICS, 2004, 120 (19) :9233-9244
[10]   PROPAGATOR AND MEAN-SQUARE DISPLACEMENT IN SINGLE-FILE SYSTEMS [J].
HAHN, K ;
KARGER, J .
JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 1995, 28 (11) :3061-3070