Electrocatalytic oxidation of oxalic and oxamic acids in aqueous media at carbon nanotube modified electrodes

被引：20
|
作者：
Ferreira, M. [1 ]
Pinto, M. F. [1 ]
Soares, O. S. G. P. [2 ]
Pereira, M. F. R. [2 ]
Orfao, J. J. M. [2 ]
Figueiredo, J. L. [2 ]
Neves, I. C. [1 ]
Fonseca, A. M. [1 ]
Parpot, P. [1 ]
机构：
[1] Univ Minho, Escola Ciencias, Ctr Quim, Dept Quim, P-4710057 Braga, Portugal
[2] Univ Porto, Dept Engn Quim, Fac Engn, Lab Catalise & Mat LCM,Lab Associado LSRE LCM, P-4200465 Oporto, Portugal
来源：
ELECTROCHIMICA ACTA | 2012年 / 60卷
关键词：
Multiwalled carbon nanotubes; Oxidation; Oxalic and oxamic acids; Electrocatalysis; Surface modification; ELECTROCHEMICAL OXIDATION; CATALYTIC-ACTIVITY; OZONATION; PHENOL; PD; REDUCTION;
D O I：
10.1016/j.electacta.2011.11.046
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The electrochemical oxidation of oxalic and oxamic acids on multiwalled carbon nanotubes (CNT) and on monometallic (Pd and Pt) and bimetallic (Pd-Cu, Pt-Cu) catalysts supported on multiwalled carbon nanotubes was investigated using cyclic voltammetry. The electrodes were prepared by dispersion of the catalytic material on Toray carbon (CT) using a Nafion/water solution. The kinetic parameters of the reactions were determined using cyclic voltammetry. Modification of Toray carbon electrode with carbon nanotubes enables the oxidation of oxalic and oxamic acids in the solvent stability region. The highest oxidation current densities were observed for the Pt-Cu/CNT/CT electrode in 0.1 M NaCl. The oxidation potentials for both oxalic and oxamic acids in this case were lower than those observed with the CNT/CT electrode. The prepared electrocatalysts show good mechanical and chemical stability. (C) 2011 Elsevier Ltd. All rights reserved.
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收藏
页码：278 / 286
页数：9
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