Rhodium(III)-triphenylphosphine complex with NNS donor thioether containing Schiff base ligand: Synthesis, spectra, electrochemistry and catalytic activity

被引：13

作者：

Biswas, Sujan ^{[1
]}

Sarkar, Deblina ^{[1
]}

Kundu, Subhankar ^{[1
]}

Roy, Puspendu ^{[1
]}

Mondal, Tapan Kumar ^{[1
]}

机构：

[1] Jadavpur Univ, Inorgan Chem Sect, Dept Chem, Kolkata 700032, India

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2015年 / 1099卷

关键词：

Rhodium(III)-triphenylphosphine complex; Thioether containing NNS donor ligand; X-ray structure; Electrochemistry; Transfer hydrogenation of ketones; DFT calculation; EFFECTIVE CORE POTENTIALS; DENSITY-FUNCTIONAL THEORY; TRANSFER HYDROGENATION; MOLECULAR CALCULATIONS; CARBONYL-COMPLEXES; IRIDIUM(III) COMPLEXES; EXCITATION-ENERGIES; OXIDATION-STATES; METAL-COMPLEXES; EFFICIENT;

D O I：

10.1016/j.molstruc.2015.06.065

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New rhodium(III)-triphenylphosphine complex, [Rh(PPh3)(L)Cl-2](PF6) (1) with thioether containing NNS donor ligand (L) (L = 2-(methylthio)-N-((pyridine-2-yl)methylene)benzenamine) has been synthesized and characterized. The pseudo octahedral geometry of the complex has been confirmed by single crystal X-ray analysis. The electronic structure, redox properties, absorption and emission properties of the complexes have been interpreted by OFT and TDDFT calculations. The complex effectively catalyzed the transfer hydrogenation reaction of ketones in 2-propanol and oxidation of alcohols in presence of NMO. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：297 / 303

页数：7

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