Study on microphase separation of Polyether-Urethane Block Copolymers

被引:0
作者
Liu, Zhen [1 ]
Xiao, Changfa [1 ]
Zhang, Yufeng [1 ]
机构
[1] Tianjin Polytech Univ, State Key Lab Hollow Fiber Membrane Mat & Proc, Tianjin 300160, Peoples R China
来源
ADVANCED RESEARCH ON MATERIAL ENGINEERING, CHEMISTRY AND BIOINFORMATICS, PTS 1 AND 2 (MECB 2011) | 2011年 / 282-283卷
关键词
polyether-urethane block copolymers; microphase separation; soft segment; hard segment; POLYURETHANES;
D O I
10.4028/www.scientific.net/AMR.282-283.557
中图分类号
TP39 [计算机的应用];
学科分类号
081203 ; 0835 ;
摘要
A set of polyether-urethane block copolymers were prepared that poly (tetramethylene oxide) PTMO was regarded as soft segment, 4,4'-methylenebis(phenyl isocyanate)(MDI) and m-diphenylamine (MDM) was regarded as hard segment in this article. The microphase separation of polyether-urethane block copolymer was investigated by using infrared spectroscopy(FTIR), differential scanning calorimetry(DSC), small-angle X-ray scattering(SAXS),there obtained that there are two phases structure in polyether-urethane block copolymers and degree of phase separation decrease with increasing hard segment weight content.
引用
收藏
页码:557 / 560
页数:4
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