Influence of temperature and concentration of water on lanthanum nitrate dissolution and crystallization

被引:0
|
作者
Harkot, J [1 ]
机构
[1] Marie Curie Sklodowska Univ, Fac Chem, Dept Inorgan Chem, PL-20031 Lublin, Poland
来源
关键词
numerical differentiation; relative water concentration; thermal analysis; thermal spectrum;
D O I
10.1023/A:1017922312386
中图分类号
O414.1 [热力学];
学科分类号
摘要
The curves of heating and cooling crystalline lanthanum nitrate were registered and numerical differentiation was carried out. The first derivatives of kinetic curves expressed as the temperature function make it possible to carry out comparative studies of dissolution and crystallization. Superposition of relative water concentration scale on the third derivative of heating and cooling curves make the analysis of stoichiometry and mechanism of hydration changes possible in the solid phase and saturated solutions.
引用
收藏
页码:621 / 626
页数:6
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