N,N′-dibromo-N,N′-1,2-ethanediylbis(benzenesulphonamide) (BNBBS):: a safe, neutral and efficient reagent for the oxidation of primary and secondary alcohols to corresponding carbonyl compounds under mild conditions

被引：0

作者：

Rostami, Amin ^{[2
]}

Mahboubifar, Marjan ^{[1
]}

Khazaei, Ardeshir ^{[1
]}

机构：

[1] Bu Ali Sina Univ, Fac Chem, Hamadan, Iran

[2] Univ Kurdistan, Dept Chem, Fac Sci, Sanandaj, Iran

来源：

SOUTH AFRICAN JOURNAL OF CHEMISTRY-SUID-AFRIKAANSE TYDSKRIF VIR CHEMIE | 2008年 / 61卷

关键词：

oxidation; alcohols; carbonyl compounds; N,N '-dibromo-N,N '-1,2-ethanediylbis(benzenesulphonamide);

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient oxidation of various types of structurally diverse alcohols to the corresponding carbonyl compounds can be carried out with N,N'-dibromo-N,N'-1,2-ethanediylbis(benzenesulphonamide) in good to high yield of products in CH2Cl2 at room temperature. Primary (aliphatic, benzylic and allylic) alcohols are oxidized with no over-oxidation to carboxylic acids.

引用

页码：9 / 12

页数：4