Biazulene diimides: a new building block for organic electronic materials

被引：108

作者：

Xin, Hanshen ^{[1
]}

Ge, Congwu ^{[1
]}

Yang, Xiaodi ^{[2
]}

Gao, Honglei ^{[1
,3
]}

Yang, Xiaochun ^{[1
]}

Gao, Xike ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Synthet & Self Assembly Chem Organ Funct, 345 Lingling Rd, Shanghai 200032, Peoples R China

[2] Fudan Univ, Lab Adv Mat, Shanghai 200433, Peoples R China

[3] Shanghai Univ, Dept Chem, Shanghai 200444, Peoples R China

来源：

CHEMICAL SCIENCE | 2016年 / 7卷 / 11期

基金：

中国国家自然科学基金;

关键词：

NEAR-IR ABSORPTION; CONJUGATED OLIGOMERS; AZULENE; DERIVATIVES; POLYMERS; SEMICONDUCTORS; CHROMOPHORES; PROTONATION; SYSTEM; BLUE;

D O I：

10.1039/c6sc02504h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Azulene, a 10-pi-electron isomer of naphthalene, is a nonbenzenoid bicyclic aromatic hydrocarbon with a beautiful blue color and a large dipole moment. We present here the first class of azulene-based aromatic diimides, 2,2'-biazulene-1,1'3,3'-tetracarboxylic diimides (BAzDIs), which comprise a 2,2'-biazulene moiety and two seven-membered imide groups. DFT calculations, thermal, optical and electrochemical properties of two BAzDI derivatives as well as single crystal analysis and the charge transport behavior were studied. The results demonstrate that BAzDIs have unique photophysical properties and are promising for organic electronic materials.

引用

收藏

页码：6701 / 6705

页数：5

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