Preconcentration with Chlorella vulgaris combined with energy dispersive X-ray fluorescence spectrometry for rapid determination of Cd in water

被引：7
作者：
Gan, Tingting [1 ,2 ]
Zhao, Nanjing [1 ,2 ]
Yin, Gaofang [1 ,2 ]
Chen, Min [1 ,2 ,3 ]
Wang, Xiang [1 ,2 ,3 ]
Hua, Hui [1 ,2 ,3 ]
机构：
[1] Chinese Acad Sci, Anhui Inst Opt & Fine Mech, Key Lab Environm Opt & Technol, Hefei 230031, Peoples R China
[2] Key Lab Opt Monitoring Technol Environm, Hefei 230031, Anhui, Peoples R China
[3] Univ Sci & Technol China, Hefei, Peoples R China
来源：
ROYAL SOCIETY OPEN SCIENCE | 2020年 / 7卷 / 05期
基金：
中国国家自然科学基金;
关键词：
cadmium; X-ray fluorescence; algae; preconcentration; rapid detection; SOLID-PHASE EXTRACTION; MULTIELEMENT DETERMINATION; CARBON NANOTUBES; GRAPHENE OXIDE; DRINKING-WATER; SAMPLES PRIOR; CADMIUM; PB; BIOSORPTION; REMOVAL;
D O I：
10.1098/rsos.200182
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Freshwater green algae Chlorella vulgaris was selected as an adsorbent, and a simple, rapid, economical and environmentally friendly method for the detection of heavy metal Cd in water samples based on preconcentration with C. vulgaris combined with energy dispersive X-ray fluorescence (EDXRF) spectrometry was proposed. Chlorella vulgaris could directly and rapidly adsorb Cd2+ without any pretreatment, and the maximum adsorption efficiency could be obtained when the contact time was 1 min with an optimal pH of 10. The obtained Cd-enriched thin samples after preconcentration with C. vulgaris by suction filtration of reaction solution had very good uniformity, which could be directly measured by EDXRF spectrometry, and the net integral fluorescence intensity of Cd K alpha characteristic peak had a very good linear relationship with the initial concentration of Cd in the range of 0.703-74.957 mu g ml(-1) with a correlation coefficient of 0.9979. When the Cd thin samples with a Cd-enriched region of 15.1 mm in diameter were formed by the developed preconcentration method with suction filtration of 10 ml reaction solution, the detection limit of this method was 0.0654 mu g ml(-1), which was lower than the maximum allowable discharge concentration of Cd in various industrial wastewaters. The proposed method was simple to operate, and could effectively remove the influence of matrix effect of water samples and effectively improve the sensitivity and stability of EDXRF spectrometry directly detecting heavy metals in water samples, which was successfully applied to detect Cd in real water samples with satisfactory results, and the recoveries ranged from 94.80% to 116.94%. Moreover, this method can be applied to the rapid detection and early warning of excessive Cd in discharged industrial wastewaters. This work will provide a methodological basis for the development of rapid and online monitoring technology and instrument of heavy metal pollutants in water.
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页数：14
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