Facile and template-free solvothermal synthesis of mesoporous/macroporous metal-organic framework nanosheets

被引：31

作者：

Zhang, Boce ^{[1
]}

Luo, Yaguang ^{[2
]}

Kanyuck, Kelsey ^{[3
]}

Saenz, Natalie ^{[2
]}

Reed, Kevin ^{[1
]}

Zavalij, Peter ^{[3
]}

Mowery, Joseph ^{[2
]}

Bauchan, Gary ^{[2
]}

机构：

[1] Univ Massachusetts, Dept Biomed & Nutr Sci, 833 Broadway St, Lowell, MA 01854 USA

[2] ARS, USDA, 10300 Baltimore Ave, Beltsville, MD 20705 USA

[3] Univ Maryland, College Pk, MD 20742 USA

来源：

RSC ADVANCES | 2018年 / 8卷 / 58期

关键词：

MOF; FABRICATION; NANOROLLS; GROWTH;

D O I：

10.1039/c8ra06576d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile and template-free solvothermal method was developed as a bottom-up approach to synthesize mesoporous/macroporous MOF nanosheets in a simple and scalable way. It was found that starting coordination complexes of different copper(II)-ligand compounds mediated the controlled growth and morphology of MOF crystals. By controlling the size and shape of the MOF crystals, the possibility to adjust and tailor the structure and performances of the assemblies was demonstrated. This work provides a bottom-up approach to synthesize MOF films and nanosheets in a simple and scalable way, which may have potential in energy and biomedical applications.

引用

页码：33059 / 33064

页数：6

共 29 条

[1] Metal organic framework mixed matrix membranes for gas separations [J].

Adams, Ryan ;

Carson, Cantwell ;

Ward, Jason ;

Tannenbaum, Rina ;

Koros, William .

MICROPOROUS AND MESOPOROUS MATERIALS, 2010, 131 (1-3) :13-20

[2] Hierarchical porous metal-organic framework monoliths [J].

Ahmed, Adham ;

Forster, Mark ;

Clowes, Rob ;

Myers, Peter ;

Zhang, Haifei .

CHEMICAL COMMUNICATIONS, 2014, 50 (92) :14314-14316

[3] Macroporous metal-organic framework microparticles with improved liquid phase separation [J].

Ahmed, Adham ;

Hodgson, Nicola ;

Barrow, Michael ;

Clowes, Rob ;

Robertson, Craig M. ;

Steiner, Alexander ;

McKeown, Paul ;

Bradshaw, Darren ;

Myers, Peter ;

Zhang, Haifei .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (24) :9085-9090

[4] Oriented growth of the metal organic framework Cu3(BTC)2(H2O)3•xH2O tunable with functionalized self-assembled monolayers [J].

Biemmi, Enrica ;

Scherb, Camilla ;

Bein, Thomas .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (26) :8054-+

[5] Supramolecular templating of hierarchically porous metal-organic frameworks [J].

Bradshaw, Darren ;

El-Hankari, Samir ;

Lupica-Spagnolo, Lucia .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5431-5443

[6] Synthesis and Structure Characterization of Copper Terephthalate Metal-Organic Frameworks [J].

Carson, Cantwell G. ;

Hardcastle, Kenneth ;

Schwartz, Justin ;

Liu, Xiaotao ;

Hoffmann, Christina ;

Gerhardt, Rosario A. ;

Tannenbaum, Rina .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (16) :2338-2343

[7] Enabling Cleaner Fuels: Desulfurization by Adsorption to Microporous Coordination Polymers [J].

Cychosz, Katie A. ;

Wong-Foy, Antek G. ;

Matzger, Adam J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (40) :14538-14543

[8]

Green MA, 2010, NAT MATER, V9, P539, DOI 10.1038/nmat2786

[9] Metal@MOF:: Loading of highly porous coordination polymers host lattices by metal organic chemical vapor deposition [J].

Hermes, S ;

Schröter, MK ;

Schmid, R ;

Khodeir, L ;

Muhler, M ;

Tissler, A ;

Fischer, RW ;

Fischer, RA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (38) :6237-6241

[10] Metal-organic framework membranes fabricated via reactive seeding [J].

Hu, Yaoxin ;

Dong, Xueliang ;

Nan, Jiangpu ;

Jin, Wanqin ;

Ren, Xiaoming ;

Xu, Nanping ;

Lee, Young Moo .

CHEMICAL COMMUNICATIONS, 2011, 47 (02) :737-739

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