Cobalt-Catalyzed, Chelation-Assisted C-H Bond Functionalization

被引：176
作者：
Yoshikai, Naohiko [1 ]
机构：
[1] Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore
来源：
SYNLETT | 2011年 / 08期
基金：
新加坡国家研究基金会;
关键词：
cobalt; C-H activation; hydroarylation; alkynes; alkenes; HIGH-PRESSURE REACTION; CARBON-HYDROGEN; REGIOSELECTIVE CYCLOMETALATION; INTERMOLECULAR HYDROARYLATION; SELECTIVE ALKENYLATION; AROMATIC KETIMINES; DIRECT ARYLATION; ACTIVATION; ALKYNES; ARYL;
D O I：
10.1055/s-0030-1259928
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
While chelation-assisted C-H bond activation by a transition-metal complex serves as a versatile platform for the development of regioselective C-H bond-functionalization reactions, the capability of first-row transition metals to catalyze such transformations has scarcely been explored. This highlight article illustrates how cobalt has recently emerged as a promising metal for chelation-assisted C-H bond functionalization.
引用
收藏
页码：1047 / 1051
页数：5
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