Solvation of 1-butyl-3-methylimidazolium hexafluorophosphate in aqueous ethanol - a green solution for dissolving 'hydrophobic' ionic liquids

被引：99
作者：
Swatloski, RP
Visser, AE
Reichert, WM
Broker, GA
Farina, LM
Holbrey, JD
Rogers, RD
机构：
[1] Univ Alabama, Dept Chem, Tuscaloosa, AL 35487 USA
[2] Univ Alabama, Ctr Green Mfg, Tuscaloosa, AL 35487 USA
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 20期
关键词：
D O I：
10.1039/b106601n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The relatively hydrophobic ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate has been found to be totally miscible with aqueous ethanol between 0.5 and 0.9 mol fraction ethanol, whereas the ionic liquid is only partially miscible with either pure water or absolute ethanol; the ability to dissolve 1-butyl-3-methylimidazolium hexafluorophosphate in a 'green' aqueous solvent system has important implications for cleaning, purification, and separations using ionic liquids.
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页码：2070 / 2071
页数：2
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