One-pot electrochemical synthesis of palladium nanoparticles and their application in the Suzuki reaction

被引：21

作者：

Deshmukh, Krishna M. ^{[1
]}

Qureshi, Ziyauddin S. ^{[1
]}

Bhatte, Kushal D. ^{[1
]}

Venkatesan, K. A. ^{[2
]}

Srinivasan, T. G. ^{[2
]}

Rao, P. R. Vasudeva ^{[2
]}

Bhanage, Bhalchandra M. ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Chem, Bombay 19, Maharashtra, India

[2] Indira Gandhi Ctr Atom Res, Div Fuel Chem, Kalpakkam 603102, Tamil Nadu, India

来源：

NEW JOURNAL OF CHEMISTRY | 2011年 / 35卷 / 12期

关键词：

TRANSITION-METAL NANOPARTICLES; COUPLING REACTIONS; IONIC LIQUIDS; ELECTRODEPOSITION; CATALYST; RECOVERY; CHLORIDE; MIYAURA;

D O I：

10.1039/c1nj20638a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel potential controllable, template free, electrodeposition/synthesis of palladium nanoparticles on an electrode surface as well as in the bulk electrolyte using ionic liquid as an electrolyte cum stabilizer is reported for the first time. The present method of preparation of palladium nanoparticles is advantageous as it eliminates the requirement of additional stabilizers or capping agents. The prepared palladium nanoparticles are characterized by different techniques such as TEM, SEM, EDAX and XPS analyses. These nanoparticles exhibited high catalytic activity for the Suzuki coupling reaction of unactivated halides in aqueous media with high TON.

引用

页码：2747 / 2751

页数：5

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