Synthesis of 1-Aza-2-borabutatriene Rhodium Complexes by Thermal Borylene Transfer from [(OC)5Mo=BN(SiMe3)2]

被引：19

作者：

Braunschweig, Holger ^{[1
]}

Ye, Qing ^{[1
]}

Damme, Alexander ^{[1
]}

Kupfer, Thomas ^{[1
]}

Radacki, Krzysztof ^{[1
]}

Wolf, Justin ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 40期

基金：

欧洲研究理事会;

关键词：

boraallene; boron; borylene complexes; rhodium; vinylidene complexes; AMINOBORYLENE COMPLEXES; ELECTRONIC-STRUCTURE; CRYSTAL-STRUCTURE; TRANSITION-METAL; CHEMISTRY; BORON; INSERTION; LIGANDS; TETRAFLUOROBUTATRIENE; FUNCTIONALIZATION;

D O I：

10.1002/anie.201104026

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Borylene on me: An unprecedented borylene transfer to metal-carbon double bonds afforded the title compounds. Preliminary studies revealed a thermally induced change of coordination mode from B-C to C-C and subsequent highly stereoselective C-H activation by the B=C bond. [(η5-C 5H5)Rh(PCy3){(B,C-η2)-(SiMe 3)2N=B=C=CH2)}] and its rearrangement product were both characterized by X-ray crystallography (see picture). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9462 / 9466

页数：5

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