Antimicrobial polyurethane coatings based on ionic liquid quaternary ammonium compounds

被引:47
作者
Yagci, M. B. [1 ]
Bolca, S. [2 ]
Heuts, J. P. A. [3 ]
Ming, W. [1 ,4 ]
de With, G. [1 ]
机构
[1] Eindhoven Univ Technol, Lab Mat & Interface Chem, NL-5600 MB Eindhoven, Netherlands
[2] Univ Ghent, Fac Biosci Engn, LabMET, B-9000 Ghent, Belgium
[3] Eindhoven Univ Technol, Polymer Chem Lab, NL-5600 MB Eindhoven, Netherlands
[4] Univ New Hampshire, Mat Sci Program, Nanostruct Polymers Res Ctr, Durham, NH 03824 USA
关键词
Antimicrobial coating; Ionic liquid; Contact killing; METAL-IONS; SURFACES; EXTRACTION; SOLVENTS; CONTACT; ANTIBACTERIAL; NANOPARTICLES; BIOCIDES; BEHAVIOR; ESTERS;
D O I
10.1016/j.porgcoat.2011.05.006
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The antimicrobial effect of ionic liquids (ILs) as comonomers in polyurethane surface coatings was investigated. Ionic liquid-containing coatings were prepared from a hydroxyl end-capped liquid oligoester and a triisocyanate crosslinker. Three different commercially available hydroxyl end-capped ionic liquids were covalently incorporated into the coatings in order to end up with antimicrobial polyurethane films. The ionic liquids used in this study were chosen because of their structural similarities to other antimicrobial quaternary ammonium compounds (QACs). Prepared films have been examined against both Gram-positive Staphylococcus aureus and Gram-negative Escherichia coli type bacteria, and showed strong antimicrobial activity. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:343 / 347
页数:5
相关论文
共 46 条
[1]   Nonleaching antimicrobial films prepared from surface-modified microfibrillated cellulose [J].
Andresen, Martin ;
Stenstad, Per ;
Moretro, Trond ;
Langsrud, Solveig ;
Syverud, Kristin ;
Johansson, Leena-Sisko ;
Stenius, Per .
BIOMACROMOLECULES, 2007, 8 (07) :2149-2155
[2]   Hybrids of silver nanoparticles with amphiphilic hyperbranched macromolecules exhibiting antimicrobial properties [J].
Aymonier, C ;
Schlotterbeck, U ;
Antonietti, L ;
Zacharias, P ;
Thomann, R ;
Tiller, JC ;
Mecking, S .
CHEMICAL COMMUNICATIONS, 2002, (24) :3018-3019
[3]   A new, simple approach to confer permanent antimicrobial properties to hydroxylated surfaces by surface functionalization [J].
Bouloussa, Othman ;
Rondelez, Francis ;
Semetey, Vincent .
CHEMICAL COMMUNICATIONS, 2008, (08) :951-953
[4]   L-carnitine esters as "soft", broad-spectrum antimicrobial amphiphiles [J].
Calvani, M ;
Critelli, L ;
Gallo, G ;
Giorgi, F ;
Gramiccioli, G ;
Santaniello, M ;
Scafetta, N ;
Tinti, MO ;
De Angelis, F .
JOURNAL OF MEDICINAL CHEMISTRY, 1998, 41 (13) :2227-2233
[5]   COMPARISON OF ACTION OF VANTOCIL CETRIMIDE AND CHLORHEXIDINE ON ESCHERICHIA COLI AND ITS SPHEROPLASTS AND PROTOPLASTS OF GRAM POSITIVE BACTERIA [J].
DAVIES, A ;
BENTLEY, M ;
FIELD, BS .
JOURNAL OF APPLIED BACTERIOLOGY, 1968, 31 (04) :448-&
[6]  
Dupont J, 2000, J BRAZIL CHEM SOC, V11, P337
[7]   New developments in catalysis using ionic liquids [J].
Gordon, CM .
APPLIED CATALYSIS A-GENERAL, 2001, 222 (1-2) :101-117
[8]   Surface Self-Concentrating Amphiphilic Quaternary Ammonium Biocides as Coating Additives [J].
Harney, Matthew B. ;
Pant, Ramesh R. ;
Fulmer, Preston A. ;
Wynne, James H. .
ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (01) :39-41
[9]   Ionic liquids with dual biological function: sweet and anti-microbial, hydrophobic quaternary ammonium-based salts [J].
Hough-Troutman, Whitney L. ;
Smiglak, Marcin ;
Griffin, Scott ;
Reichert, W. Matthew ;
Mirska, Ilona ;
Jodynis-Liebert, Jadwiga ;
Adamska, Teresa ;
Nawrot, Jan ;
Stasiewicz, Monika ;
Rogers, Robin D. ;
Pernak, Juliusz .
NEW JOURNAL OF CHEMISTRY, 2009, 33 (01) :26-33
[10]  
Juergensen L, 2000, ENVIRON TOXICOL, V15, P174, DOI 10.1002/1522-7278(2000)15:3<174::AID-TOX4>3.3.CO