Study of citrate adsorbed on the Au(111) surface by scanning probe microscopy

被引:51
作者
Lin, Y
Pan, GB
Su, GJ
Fang, XH [1 ]
Wan, LJ
Bai, CL
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
关键词
D O I
10.1021/la0350251
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A combined scanning probe microscopy study of citrate adsorbed on Au(111) has been conducted. The adlayer structure of citrate on Au(111) is imaged using in situ scanning tunneling microscopy for the first time. Citrate anions are found to form stable and well-ordered adlayers with (4 x 2root3) symmetry. The effect of the citrate adlayer on the interaction between the gold surface and fibrinogen, the protein that has a major role in blood coagulation, has been investigated by atomic force microscopy. The results indicate that citrate modification may change the biocompatibility of gold.
引用
收藏
页码:10000 / 10003
页数:4
相关论文
共 32 条
[11]   CITRATE CONFORMATION AND CHELATION - ENZYMATIC IMPLICATIONS [J].
GLUSKER, JP .
ACCOUNTS OF CHEMICAL RESEARCH, 1980, 13 (10) :345-352
[12]   Nucleation, growth, and pseudo-polymorphic behavior of citric acid as monitored in situ by attenuated total reflection Fourier transform infrared spectroscopy [J].
Groen, H ;
Roberts, KJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (43) :10723-10730
[13]   Formation of colloidal silver nanoparticles: Capping action of citrate [J].
Henglein, A ;
Giersig, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (44) :9533-9539
[14]   In situ scanning tunneling microscopy in electrolyte solutions [J].
Itaya, K .
PROGRESS IN SURFACE SCIENCE, 1998, 58 (03) :121-247
[15]   Atomic force microscopy of biomaterials surfaces and interfaces [J].
Jandt, KD .
SURFACE SCIENCE, 2001, 491 (03) :303-332
[16]  
Lipkowski J., 1992, ADSORPTION MOL METAL
[17]   Extended surface chirality from supramolecular assemblies of adsorbed chiral molecules [J].
Lorenzo, MO ;
Baddeley, CJ ;
Muryn, C ;
Raval, R .
NATURE, 2000, 404 (6776) :376-379
[18]   Hydrogen evolution from solutions of citric acids [J].
Marinovic, V ;
Despic, AR .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 431 (01) :127-132
[19]  
Martín H, 2000, LANGMUIR, V16, P2915, DOI 10.1021/1a91130s
[20]   AMPEROMETRIC FLOW-INJECTION DETERMINATION OF CITRIC-ACID IN FOOD USING FREE CITRATE LYASE AND CO-IMMOBILIZED OXALACETATE DECARBOXYLASE AND PYRUVATE OXIDASE [J].
MATSUMOTO, K ;
TSUKATANI, T ;
OKAJIMA, Y .
ELECTROANALYSIS, 1995, 7 (06) :527-530