Study of citrate adsorbed on the Au(111) surface by scanning probe microscopy

被引:51
作者
Lin, Y
Pan, GB
Su, GJ
Fang, XH [1 ]
Wan, LJ
Bai, CL
机构
[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China
关键词
D O I
10.1021/la0350251
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A combined scanning probe microscopy study of citrate adsorbed on Au(111) has been conducted. The adlayer structure of citrate on Au(111) is imaged using in situ scanning tunneling microscopy for the first time. Citrate anions are found to form stable and well-ordered adlayers with (4 x 2root3) symmetry. The effect of the citrate adlayer on the interaction between the gold surface and fibrinogen, the protein that has a major role in blood coagulation, has been investigated by atomic force microscopy. The results indicate that citrate modification may change the biocompatibility of gold.
引用
收藏
页码:10000 / 10003
页数:4
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