Amplification of Chirality in Photopatterned 3D Nanostructures of Chiral/Achiral Mixtures

被引：0
作者：
Jee, Hongsub [1 ]
Chen, Guanying [2 ]
Lee, Jaehyeong [1 ]
机构：
[1] Sungkyunkwan Univ, Dept Elect & Comp Engn, Suwon 16419, South Korea
[2] Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150001, Peoples R China
来源：
APPLIED SCIENCES-BASEL | 2022年 / 12卷 / 17期
关键词：
chiral; achiral; circular dichroism; optical activity; two-photon lithography; photopatterning; OPTICAL-ACTIVITY; POLY(FLUORENE-ALT-BENZOTHIADIAZOLE) PFBT; NANOCOMPOSITES; POLYMERS; HOMOPOLYMERS; BLENDS;
D O I：
10.3390/app12178702
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dispersion of a chiral polymer in a polymerizable matrix can amplify the chirality of the material, and a helical conformation of the chiral material within the polymerized SU-8 excessively increased the circular dichroism. Here, we demonstrate the fabrication of three-dimensional nanostructures of chiral/achiral mixtures by two-photon lithography. The irradiation of light and annealing caused local changes in the chiral material and finally led to the enhancement of the optical properties. The demonstration of a photopatternable chiral material could expand the usage of optical materials for various applications.
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页数：8
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