Sn-MCM-41 - a heterogeneous selective catalyst for the Baeyer-Villiger oxidation with hydrogen peroxide

被引：147
|
作者：
Corma, A
Navarro, MT
Nemeth, L
Renz, M
机构：
[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[2] UOP Res Ctr, Des Plaines, IL 60017 USA
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 21期
关键词：
D O I：
10.1039/b105927k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new heterogeneous catalyst, Sn-MCM-41, is described for the Baeyer-Villiger reaction with hydrogen peroxide which selectively activates the carbonyl function for the nucleophilic attack by the oxidant, with high chemoselectivities when double bonds are present in the molecule.
引用
收藏
页码：2190 / 2191
页数：2
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