Synthesis and crystal structure of a novel monomeric di-butyltin dicarboxylate:: nBu2Sn[O2CCH2CH(4-ClC6H4)Ge(OCH2CH2)3N]2•H2O

被引：0
|
作者：
Song, XQ [1 ]
Yang, ZQ [1 ]
Xie, QL [1 ]
机构：
[1] Nankai Univ, Natl Lab ElementoOrgan Chem, Tianjin 300071, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 1999年 / 18卷 / 02期
关键词：
diorganotin dicarboxylate; crystal structure; synthesis;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
(Bu2Sn)-Bu-II [O2CCH2CH (4-ClC6H4) Ge (OCH2CH2)(3)N](2) . H2O (M-r = 1053. 66) is an air-stable compound which crystallizes in the monoclinic space group C2/c with a = 21. 182(5), b = 12. 174(3), c = 17. 108(4) Angstrom, beta = 99. 59(2)degrees, V = 4350(3) Angstrom(3), Z = 4, F(000) = 2104, mu = 2. 104 mm(-1). The refinement of structure with I greater than or equal to 3 sigma(I) for 1819 reflections converged at R = 0. 045. The coordination geometry around the Sn atom is best described as an askew-pentagonal bipyramid, in which four carboxylate oxygen atoms ( Sn(1)-O(5), Sn(1)-O(5a) = 2. 099 Angstrom and Sn(1)-O(4), Sn(1)-O(4a) = 2. 158 Angstrom) and an oxygen atom from an aqua ligand comprise the pentagonal planer with two butyl groups occupying axial positions.
引用
收藏
页码：84 / 88
页数：5
相关论文
共 50 条
  • [41] Synthesis and Crystal Structure of the Copper Complex {[Cu（CH3COO）2（bbtz）]（H2O）2}n
    ZHANG Yong ZHANG Yu-Mei LIU Xun-Gao LI Bao-Long② (Key Laboratory of Organic Synthesis of Jiangsu Province
    结构化学, 2005, (10) : 1129 - 1132
  • [42] Synthesis and crystal structure of the copper complex {[Cu(CH3COO)2(bbtz)](H2O)2}n
    Zhang, Y
    Zhang, YM
    Liu, XG
    Li, BL
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2005, 24 (10) : 1129 - 1132
  • [43] Synthesis and crystal structure of [OsFPy5][BF4]•H2O•CH2Cl2
    Kolf, S
    Preetz, W
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1999, 54 (01): : 54 - 56
  • [44] Synthesis and the network structure of the supramolecular compound [NEt4][Mn(salophen)(H2O)2]2[Fe(CN)6]•H2O•CH3OH
    Li, SN
    Li, J
    Tang, ZX
    Zhou, ZY
    ACTA CHIMICA SINICA, 2001, 59 (01) : 78 - 83
  • [45] Synthesis and crystal structure of cadmium(II) complex [Cd(H2O)(CH3OC6H4COO)2]n
    Zhao, QH
    Ma, YP
    Wang, QH
    Fang, RB
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2002, 21 (05) : 513 - 516
  • [46] Synthesis and crystal structure of [Nd(H2O)2]2(C2O4)3
    J.C. Trombe
    J. Jaud
    Journal of Chemical Crystallography, 2003, 33 : 19 - 26
  • [47] Synthesis and crystal structure of europium(II) tartrate tetrahydrate, [Eu(C4H4O6) (H2O)2](H2O)2
    Starynowicz, P
    Meyer, G
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2000, 626 (12): : 2441 - 2442
  • [48] Synthesis and crystal structure of Zn[(C6H5N3)4(H2O)2](ClO4)2 and Cu[(C6H5N3)4(H2O)2](CIO4)2
    Li, LX
    Wang, XQ
    Shen, GQ
    Wang, RJ
    Shen, DZ
    INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (07) : 453 - 457
  • [49] Synthesis and crystal structure of [Nd(H2O)2]2(C2O4)3
    Trombe, JC
    Jaud, J
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2003, 33 (01) : 19 - 26
  • [50] Synthesis and Crystal Structure of a Heterometallic Chain Coordination Polymer:{[Ni2Mn2L2(CH3CH2OH)(H2O)]·CH3OH·2H2O}n
    李付安
    王守斌
    陶偌偈
    结构化学, 2010, 29 (01) : 63 - 68
12345