Influence of various reaction parameters on the process for preparation of SiO2/TiO2 Core-Shell Particles

被引：1

作者：

You, Jhin-Hong ^{[1
]}

Kuo, Yi-Yin ^{[1
]}

Hsu, Keh-Ying ^{[1
]}

机构：

[1] Chung Yuan Christian Univ, Dept Chem Engn, Chungli 32023, Taiwan

来源：

JOURNAL OF NANO RESEARCH | 2015年 / 33卷

关键词：

core-shell particle; chelating agent; SiO2; TiO2; SOL-GEL SYNTHESIS; PHOTOCATALYTIC-OXIDATION; THIN-FILMS; TIO2; COMPOSITE; IRRADIATION; NANOWIRES; CATALYST; SENSOR;

D O I：

10.4028/www.scientific.net/JNanoR.33.27

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

This study aims to describe the preparation and characterization of SiO2/TiO2 core-shell particles. In order to prepare the homogenous SiO2/TiO2 inorganic compounds by sol-gel process, SiO2 particles were used as the core, AcAc served as a chelating agent to chelate with TTIP (which was used as the precursor to TiO2), and PEG was added to stabilize the hydrolysis/condensation process. In addition, the ionic surfactant (SDS) and the nonionic surfactant (PVP) dispersed the core-shell particles. In order to improve the crystal structure, a high temperature was used to calcine the core-shell particles. The influence of various reaction parameters on the size, morphology and composition of the particles was also investigated. The properties of the particles were analyzed by electron microscopy, fourier transform infrared analysis, thermogravimetric analysis and powder X-ray diffraction.

引用

页码：27 / 37

页数：11

共 28 条

[1] Structural characterization of titanium-oxo-polymers synthesized in the presence of protons or complexing ligands as inhibitors [J].

Blanchard, J ;

Ribot, F ;

Sanchez, C ;

Bellot, PV ;

Trokiner, A .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 265 (1-2) :83-97

[2] Photocatalytic Degradation of Benzene Derivatives on TiO2 Catalyst [J].

Bougheloum, Ch. ;

Messalhi, A. .

PROCEEDINGS OF THE JMSM 2008 CONFERENCE, 2009, 2 (03) :1055-1058

[3] Novel thiourea-modified magnetic ion-imprinted chitosan/TiO2 composite for simultaneous removal of cadmium and 2,4-dichlorophenol [J].

Chen, Anwei ;

Zeng, Guangming ;

Chen, Guiqiu ;

Hu, Xinjiang ;

Yan, Ming ;

Guan, Song ;

Shang, Cui ;

Lu, Lunhui ;

Zou, Zhengjun ;

Xie, Gengxin .

CHEMICAL ENGINEERING JOURNAL, 2012, 191 :85-94

[4] Chelation and solvent effect on the preparation of titania colloids [J].

Chen, Hung-Jen ;

Wang, Leeyih ;

Chiu, Wen-Yen .

MATERIALS CHEMISTRY AND PHYSICS, 2007, 101 (01) :12-19

[5] Synthesis of nano-sized TiO2/poly(AA-co-MMA) composites by heterocoagulation and blending with PET [J].

Chen, Jui-Hung ;

Dai, Chi-An ;

Chen, Hung-Jen ;

Chien, Pei-Chi ;

Chiu, Wen-Yen .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2007, 308 (01) :81-92

[6] Enhanced Photocatalytic Activity of Nitrogen Doped TiO2 Anatase Nano-Particle under Simulated Sunlight Irradiation [J].

Cheng, Xiuwen ;

Yu, Xiujuan ;

Xing, Zipeng ;

Wan, Jiafeng .

2012 INTERNATIONAL CONFERENCE ON FUTURE ENERGY, ENVIRONMENT, AND MATERIALS, PT A, 2012, 16 :598-605

[7] The surface science of titanium dioxide [J].

Diebold, U .

SURFACE SCIENCE REPORTS, 2003, 48 (5-8) :53-229

[8] Sol-gel synthesis of titania-alumina catalyst supports [J].

Kaneko, EY ;

Pulcinelli, SH ;

da Silva, VT ;

Santilli, CV .

APPLIED CATALYSIS A-GENERAL, 2002, 235 (1-2) :71-78

[9] Synthesis of monodisperse fluorescent core-shell silica particles using a modified Stober method for imaging individual particles in dense colloidal suspensions [J].

Lee, MH ;

Beyer, FL ;

Furst, EM .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 288 (01) :114-123

[10] Elaboration and characterization of thin films of TiO2 prepared by sol-gel process [J].

Legrand-Buscema, C ;

Malibert, C ;

Bach, S .

THIN SOLID FILMS, 2002, 418 (02) :79-84

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