Crown ethers as a tool for the preparation of molecularly imprinted polymers

被引：0

作者：

Andersson, HS

Ramström, O

机构：

[1] Univ Kalmar, Inst Nat Sci, Bioorgan Chem Lab, S-39129 Kalmar, Sweden

[2] Univ Lund, Ctr Chem, Dept Pure & Appl Biochem, S-22100 Lund, Sweden

来源：

JOURNAL OF MOLECULAR RECOGNITION | 1998年 / 11卷 / 1-6期

关键词：

crown ether; HPLC; host-guest chemistry; molecular imprinting technology; molecular recognition; molecularly imprinted polymers; supramolecular chemistry;

D O I：

10.1002/(SICI)1099-1352(199812)11:1/6<103::AID-JMR400>3.0.CO;2-C

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Molecularly imprinted polymers have been prepared against aniline and a bis-aniline compound, making use of a crown ether (18-crown-6) to solubilize the monomer-template complexes, Subsequent chromatographic rebinding studies in the absence of crown ether revealed regioselectivity for the templates in the respective polymers. This study indicates that crown ethers can be potentially useful in conjunction with molecular imprinting to solubilize and imprint organic solvent-insoluble compounds. (C) 1998 John Wiley & Sons, Ltd.

引用

页码：103 / 106

页数：4

共 17 条

[1]

Andersson HS, 1997, RRD PURE APPL CHEM, V1, P133

[2]

Andersson HS, 1996, J MOL RECOGNIT, V9, P675, DOI 10.1002/(SICI)1099-1352(199634/12)9:5/6<675::AID-JMR320>3.0.CO

[3]

2-C

[4] MOLECULAR RECOGNITION IN SYNTHETIC-POLYMERS - PREPARATION OF CHIRAL STATIONARY PHASES BY MOLECULAR IMPRINTING OF AMINO-ACID AMIDES [J].