Remarkable structural transformation of [Zn(tza)2] during recrystallization, syntheses and crystal structures of [M(tza)2] (M = Zn, Cd, Mn, Co; Htza = tetrazole-1-acetic acid)

被引：77

作者：

Dong, Wen-Wen ^{[1
,2
]}

Zhao, Jun ^{[1
,2
]}

Xu, Li ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2008年 / 8卷 / 08期

关键词：

D O I：

10.1021/cg7012182

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The substitution reactions of M(CH3CH2CO2)(2) and Htza afford the crystalline precipitates-of [Cd(tza)(2)] (1), [Mn(tza)(2)] (2), [Co(tza)(2)] (3), and beta-[Zn(tza)(2)] (5). The recrystallization of 5 leads to the formation of alpha-[Zn(tza)(2)] (4). X-ray powder diffraction of 1-5 reveal that 1, 2, 3, and 5 are allomers, but 4 and 5 are isomers, revealing the unprecedented structural transformation during the process of recrystallization. Compounds 1-4 have been characterized by X-ray single-crystal crystallography, IR, and magnetism analysis. Structural analyses and comparison of 1-4 detail the structural evolution of from beta-[Zn(tza)(2)] (5) to alpha-[Zn(tza)(2)] (4) and possible driving force has been proposed. The interactions between the Mn-II ions of 2 have been observed as weakly antiferromagnetic.

引用

页码：2882 / 2886

页数：5

共 37 条

[1] Carlucci L, 1999, ANGEW CHEM INT EDIT, V38, P3488
[2] Weak metamagnetic-like 1D manganese(II) complex with a double μ1,1-azido bridge:: A structure and magnetic study
Das, A
Rosair, GM
El Fallah, MS
Ribas, J
Mitra, S
[J]. INORGANIC CHEMISTRY, 2006, 45 (08) : 3301 - 3306
[3] Low-spin state structure of [Fe(chloroethyltetrazole)6] (BF4)2 obtained from synchrotron powder diffraction data
Dova, E
Peschar, R
Takata, M
Nishibori, E
Schenk, H
Stassen, AF
Haasnoot, JG
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (20) : 5855 - 5865
[4] High-spin- and low-spin-state structures of [Fe(chloroethyltetrazole)6](ClO4)2 from synchrotron powder diffraction data
Dova, Eva
Peschar, Rene
Sakata, Makoto
Kato, Kenichi
Schenk, Henk
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (19) : 5043 - 5052
[5] Structural and magnetic properties of carboxylato-bridged manganese(II) complexes involving tetradentate ligands:: Discrete complex and 1D polymers.: Dependence of J on the nature of the carboxylato bridge
Durot, S
Policar, C
Pelosi, G
Bisceglie, F
Mallah, T
Mahy, JP
[J]. INORGANIC CHEMISTRY, 2003, 42 (24) : 8072 - 8080
[6] MAGNETISM IN 1-DIMENSIONAL SYSTEMS - HEISENBERG MODEL FOR INFINITE SPIN
FISHER, ME
[J]. AMERICAN JOURNAL OF PHYSICS, 1964, 32 (05) : 343 - +
[7] Guest-dependent spin crossover in a nanoporous molecular framework material
Halder, GJ
Kepert, CJ
Moubaraki, B
Murray, KS
Cashion, JD
[J]. SCIENCE, 2002, 298 (5599) : 1762 - 1765
[8] Controlled aggregation of heterometallic nanoscale Cu12Ln6 clusters (Ln = GdIII or NdIII) into 2D coordination polymers
He, F
Tong, ML
Yu, XL
Chen, XM
[J]. INORGANIC CHEMISTRY, 2005, 44 (03) : 559 - 565
[9] Crystal-to-crystal transformation from a chain polymer to a two-dimensional network at low temperatures
Hu, CH
Englert, U
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (15) : 2281 - 2283
[10] Structural variation in manganese complexes: Synthesis and characterization of manganese complexes from carboxylate-containing chelating ligands
Iikura, H
Nagata, T
[J]. INORGANIC CHEMISTRY, 1998, 37 (18) : 4702 - 4711

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