Synthesis of threo- and erythro-bis(2,2′-tetrahydrofuran).: A novel serendipitous synthesis of a spiroketal

被引：9
|
作者：
Kelly, DR [1 ]
Nally, J [1 ]
机构：
[1] Univ Wales Coll Cardiff, Dept Chem, Cardiff CF1 3TB, S Glam, Wales
来源：
TETRAHEDRON LETTERS | 1999年 / 40卷 / 11期
关键词：
D O I：
10.1016/S0040-4039(99)00173-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Racemic threo-bis(2,2'-tetrahydrofuran) and meso-erythro-bis(2,2'-tetrahydrofuran) have been prepared by stereochemically unambiguous routes. Treatment of 2-(1'-bromo-4'-hydroxybutyl)-tetrahydrofuran with base or silver(I) tetrafluoroborate effected cyclisation to 1,6-dioxa-spiro[4.5]decane. (C) 1999 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2209 / 2212
页数：4
相关论文
共 50 条
12345