Synthesis, crystal structure and magnetic property of a novel Cobalt(H) complex with 4-(p-bromophenyl)-3,5-bis(2-pyridyl)-1,2,4-triazole

被引：0

作者：

Qi Li ^{[1
]}

Zhu Dun-Ru ^{[1
]}

Xie Da-Jing ^{[1
]}

Wu Yan-Fei ^{[1
]}

Shen Xuan ^{[1
]}

机构：

[1] Nanjing Univ Technol, State Key Lab Mat Oriented Chem Engn, Coll Chem & Chem Engn, Nanjing 210009, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 24卷 / 06期

关键词：

cobalt(II) complex; crystal structure; triazole; magnetic property;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new cobalt(II) complex, [CoL25(NCS)(2)], [L-5=4-(p-bromophenyl)-3,5-bis(2-pyridyl)-1,2,4-triazole], was synthesized and its structure was determined by single crystal X-ray diffraction, FTIR and ESI-MS spectroscopy. The complex crystallizes in triclinic system with space group P1. The cobalt atom is in a distorted octahedral environment with two bidentate chelating L ligands in the equatorial plane and two NCS- ions in the axial positions. Magnetic measurements show that the complex is in a high-spin state in the 1.8 similar to 300 K range.

引用

页码：868 / 872

页数：5

共 27 条

[1] MULTIPLY-CHARGED IONS OF RUTHENIUM(II), RHODIUM(III) AND COBALT(III) COMPLEXES IN ELECTROSPRAY-IONIZATION MASS-SPECTROMETRY [J].