Chemistry and physics of a single atomic layer: strategies and challenges for functionalization of graphene and graphene-based materials

被引:443
作者
Yan, Liang [4 ,5 ]
Zheng, Yue Bing [1 ,2 ,3 ]
Zhao, Feng [4 ,5 ]
Li, Shoujian [6 ]
Gao, Xingfa [4 ,5 ]
Xu, Bingqian [7 ,8 ]
Weiss, Paul S. [1 ,2 ,3 ]
Zhao, Yuliang [4 ,5 ,6 ]
机构
[1] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA 90095 USA
[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
[3] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA
[4] Chinese Acad Sci, Key Lab Biomed Effects Nanomat & Nanosafety, Natl Ctr Nanosci & Technol China, Beijing 100190, Peoples R China
[5] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China
[6] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
[7] Univ Georgia, Fac Engn & Nanoscale Sci, Athens, GA 30602 USA
[8] Univ Georgia, Ctr Engn, Athens, GA 30602 USA
关键词
CHEMICALLY CONVERTED GRAPHENE; WALLED CARBON NANOTUBES; HIGH-YIELD PRODUCTION; LARGE-AREA; METAL NANOPARTICLES; GRAPHITE OXIDE; EPITAXIAL GRAPHENE; DIAZONIUM FUNCTIONALIZATION; SIDEWALL FUNCTIONALIZATION; PALLADIUM NANOPARTICLES;
D O I
10.1039/c1cs15193b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Graphene has attracted great interest for its superior physical, chemical, mechanical, and electrical properties that enable a wide range of applications from electronics to nanoelectromechanical systems. Functionalization is among the significant vectors that drive graphene towards technological applications. While the physical properties of graphene have been at the center of attention, we still lack the knowledge framework for targeted graphene functionalization. In this critical review, we describe some of the important chemical and physical processes for graphene functionalization. We also identify six major challenges in graphene research and give perspectives and practical strategies for both fundamental studies and applications of graphene (315 references).
引用
收藏
页码:97 / 114
页数:18
相关论文
共 315 条
[1]  
AKASAKA T, CHEM NANOCARBONS, P433
[2]   The effect of heat treatment on formation of graphene thin films from graphene oxide nanosheets [J].
Akhavan, O. .
CARBON, 2010, 48 (02) :509-519
[3]   Stable Aqueous Dispersions of Noncovalently Functionalized Graphene from Graphite and their Multifunctional High-Performance Applications [J].
An, Xiaohong ;
Simmons, Trevor John ;
Shah, Rakesh ;
Wolfe, Christopher ;
Lewis, Kim M. ;
Washington, Morris ;
Nayak, Saroj K. ;
Talapatra, Saikat ;
Kar, Swastik .
NANO LETTERS, 2010, 10 (11) :4295-4301
[4]  
[Anonymous], 1994, The Economics of the Nuclear Fuel Cycle
[5]   Building blocks for integrated graphene circuits [J].
Areshkin, Denis A. ;
White, Carter T. .
NANO LETTERS, 2007, 7 (11) :3253-3259
[6]   Graphene-like nano-sheets for surface acoustic wave gas sensor applications [J].
Arsat, R. ;
Breedon, M. ;
Shafiei, M. ;
Spizziri, P. G. ;
Gilje, S. ;
Kaner, R. B. ;
Kalantar-Zadeh, K. ;
Wlodarski, W. .
CHEMICAL PHYSICS LETTERS, 2009, 467 (4-6) :344-347
[7]  
Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/nnano.2010.132, 10.1038/NNANO.2010.132]
[8]  
Balog R, 2010, NAT MATER, V9, P315, DOI [10.1038/nmat2710, 10.1038/NMAT2710]
[9]   Atomic Hydrogen Adsorbate Structures on Graphene [J].
Balog, Richard ;
Jorgensen, Bjarke ;
Wells, Justin ;
Laegsgaard, Erik ;
Hofmann, Philip ;
Besenbacher, Flemming ;
Hornekaer, Liv .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8744-+
[10]  
Banhart F, 2011, ACS NANO, V5, P26, DOI [10.1021/nn102598m, 10.1016/B978-0-08-102053-1.00005-3]