Amorphous molybdenum sulfide and its Mo-S motifs: Structural characteristics, synthetic strategies, and comprehensive applications

被引：34

作者：

Chang, Cheng ^{[1
,2
]}

Wang, Longlu ^{[1
,2
]}

Xie, Lingbin ^{[3
,4
]}

Zhao, Weiwei ^{[3
,4
]}

Liu, Shujuan ^{[3
,4
]}

Zhuang, Zechao ^{[6
]}

Liu, Shijie ^{[1
,2
]}

Li, Jianmin ^{[1
,2
]}

Liu, Xia ^{[5
]}

Zhao, Qiang ^{[1
,2
,3
,4
]}

机构：

[1] Nanjing Univ Posts & Telecommun NJUPT, Coll Elect & Opt Engn, Nanjing 210023, Peoples R China

[2] Nanjing Univ Posts & Telecommun NJUPT, Coll Flexible Elect Future Technol, Nanjing 210023, Peoples R China

[3] Nanjing Univ Posts & Telecommun, Key Lab Organ Elect & Informat Displays, Nanjing 210023, Peoples R China

[4] Nanjing Univ Posts & Telecommun, Jiangsu Key Lab Biosensots, Inst Adv Mat IAM, Nanjing 210023, Peoples R China

[5] Qingdao Univ, Coll Chem & Chem Engn, Qingdao 266071, Peoples R China

[6] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

NANO RESEARCH | 2022年 / 15卷 / 09期

基金：

中国国家自然科学基金;

关键词：

amorphous molybdenum sulfide; Mo-S motifs; structural characterization; synthetic strategies; comprehensive applications; HYDROGEN EVOLUTION REACTION; RAY-ABSORPTION SPECTROSCOPY; CHALCOGEN-BASED AEROGELS; REDUCED GRAPHENE OXIDE; THERMAL-DECOMPOSITION; ACTIVE-SITES; SULFUR-ATOMS; ELECTRODE MATERIALS; HIGH-CAPACITY; HEAVY-METALS;

D O I：

10.1007/s12274-022-4507-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Amorphous materials are one kind of nonequilibrium materials and have become one of the most active research fields. Compared with crystalline solids, the theory of amorphous materials is still in infancy because their characteristic of atomic arrangement is more like liquid and has no long-range periodicity. Recently, as the representative of amorphous materials, amorphous molybdenum sulfide (a-MoSx) with unique physical and chemical properties has been studied extensively. However, considerable debate surrounds the structure-property relationships of a-MoSx owing to its diverse Mo-S motifs. Herein, we summarize recent discoveries and research results regarding a-MoSx, whose structural characteristics, synthetic strategies, formation criteria, and comprehensive applications are discussed in detail. Finally, this review is ended with our personal insights and critical outlooks over the development of a-MoSx.

引用

页码：8613 / 8635

页数：23

共 235 条

[31] Oxygen-incorporated MoX (X: S, Se or P) nanosheets via universal and controlled electrochemical anodic activation for enhanced hydrogen evolution activity [J].

Deng, Yunqie ;

Liu, Zhen ;

Wang, Aizhu ;

Sun, Dehui ;

Chen, Yuke ;

Yang, Linjing ;

Pang, Jinbo ;

Li, Hai ;

Li, Haidong ;

Liu, Hong ;

Zhou, Weijia .

NANO ENERGY, 2019, 62 :338-347

[32] One-Dimensional Metal-Oxide Nanostructures: Recent Developments in Synthesis, Characterization, and Applications [J].

Devan, Rupesh S. ;

Patil, Ranjit A. ;

Lin, Jin-Han ;

Ma, Yuan-Ron .

ADVANCED FUNCTIONAL MATERIALS, 2012, 22 (16) :3326-3370

[33] THERMAL-DECOMPOSITION OF (NH4)2[MO3S(S2)6] . NH2O [J].

DIEMANN, E ;

MULLER, A ;

AYMONINO, PJ .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1981, 479 (08) :191-198

[34] THIO AND SELENO COMPOUNDS OF TRANSITION-METALS WITH DO CONFIGURATION [J].

DIEMANN, E ;

MULLER, A .

COORDINATION CHEMISTRY REVIEWS, 1973, 10 (1-2) :79-122

[35] Efficient Electrocatalytic and Photoelectrochemical Hydrogen Generation Using MoS2 and Related Compounds [J].

Ding, Qi ;

Song, Bo ;

Xu, Ping ;

Jin, Song .

CHEM, 2016, 1 (05) :699-726

[36] N-Doped amorphous MoSx for the hydrogen evolution reaction [J].

Ding, Ruimin ;

Wang, Mengchao ;

Wang, Xianfen ;

Wang, Huixiang ;

Wang, Liancheng ;

Mu, Yuewen ;

Lv, Baoliang .

NANOSCALE, 2019, 11 (23) :11217-11226

[37] Sulfur-Rich (NH4)2Mo3S13 as a Highly Reversible Anode for Sodium/Potassium-Ion Batteries [J].

Ding, Shuangshuang ;

Zhou, Bingxin ;

Chen, Changmiao ;

Huang, Zhao ;

Li, Pengchao ;

Wang, Shuangyin ;

Cao, Guozhong ;

Zhang, Ming .

ACS NANO, 2020, 14 (08) :9626-9636

[38] Molybdenum Polysulfide Chalcogels as High-Capacity, Anion-Redox-Driven Electrode Materials for Li-Ion Batteries [J].

Doan-Nguyen, Vicky V. T. ;

Subrahmanyam, Kota S. ;

Butala, Megan M. ;

Gerbec, Jeffrey A. ;

Islam, Saiful M. ;

Kanipe, Katherine N. ;

Wilson, Catrina E. ;

Balasubramanian, Mahalingam ;

Wiaderek, Kamila M. ;

Borkiewicz, Olaf J. ;

Chapman, Karena W. ;

Chupas, Peter J. ;

Moskovits, Martin ;

Dunn, Bruce S. ;

Kanatzidis, Mercouri G. ;

Seshadri, Ram .

CHEMISTRY OF MATERIALS, 2016, 28 (22) :8357-8365

[39] Electrodeposited Mo3S13 Films from (NH4)2Mo3S13•2H2O for Electrocatalysis of Hydrogen Evolution Reaction [J].

Du, Kuangzhou ;

Zheng, Lirong ;

Wang, Tanyuan ;

Zhuo, Junqiao ;

Zhu, Zhiwei ;

Shao, Yuanhua ;

Li, Meixian .

ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (22) :18675-18681

[40] Insights into the Electrochemical Polymerization of [Mo3S13]2- Generating Amorphous Molybdenum Sulfide [J].

Duong, Tuan M. ;

Nguyen, Phuc D. ;

Nguyen, Anh D. ;

Le, Ly T. ;

Nguyen, Loan T. ;

Pham, Hai, V ;

Tran, Phong D. .

CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (60) :13676-13682

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