Amorphous molybdenum sulfide and its Mo-S motifs: Structural characteristics, synthetic strategies, and comprehensive applications

被引：34

作者：

Chang, Cheng ^{[1
,2
]}

Wang, Longlu ^{[1
,2
]}

Xie, Lingbin ^{[3
,4
]}

Zhao, Weiwei ^{[3
,4
]}

Liu, Shujuan ^{[3
,4
]}

Zhuang, Zechao ^{[6
]}

Liu, Shijie ^{[1
,2
]}

Li, Jianmin ^{[1
,2
]}

Liu, Xia ^{[5
]}

Zhao, Qiang ^{[1
,2
,3
,4
]}

机构：

[1] Nanjing Univ Posts & Telecommun NJUPT, Coll Elect & Opt Engn, Nanjing 210023, Peoples R China

[2] Nanjing Univ Posts & Telecommun NJUPT, Coll Flexible Elect Future Technol, Nanjing 210023, Peoples R China

[3] Nanjing Univ Posts & Telecommun, Key Lab Organ Elect & Informat Displays, Nanjing 210023, Peoples R China

[4] Nanjing Univ Posts & Telecommun, Jiangsu Key Lab Biosensots, Inst Adv Mat IAM, Nanjing 210023, Peoples R China

[5] Qingdao Univ, Coll Chem & Chem Engn, Qingdao 266071, Peoples R China

[6] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

NANO RESEARCH | 2022年 / 15卷 / 09期

基金：

中国国家自然科学基金;

关键词：

amorphous molybdenum sulfide; Mo-S motifs; structural characterization; synthetic strategies; comprehensive applications; HYDROGEN EVOLUTION REACTION; RAY-ABSORPTION SPECTROSCOPY; CHALCOGEN-BASED AEROGELS; REDUCED GRAPHENE OXIDE; THERMAL-DECOMPOSITION; ACTIVE-SITES; SULFUR-ATOMS; ELECTRODE MATERIALS; HIGH-CAPACITY; HEAVY-METALS;

D O I：

10.1007/s12274-022-4507-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Amorphous materials are one kind of nonequilibrium materials and have become one of the most active research fields. Compared with crystalline solids, the theory of amorphous materials is still in infancy because their characteristic of atomic arrangement is more like liquid and has no long-range periodicity. Recently, as the representative of amorphous materials, amorphous molybdenum sulfide (a-MoSx) with unique physical and chemical properties has been studied extensively. However, considerable debate surrounds the structure-property relationships of a-MoSx owing to its diverse Mo-S motifs. Herein, we summarize recent discoveries and research results regarding a-MoSx, whose structural characteristics, synthetic strategies, formation criteria, and comprehensive applications are discussed in detail. Finally, this review is ended with our personal insights and critical outlooks over the development of a-MoSx.

引用

页码：8613 / 8635

页数：23

共 235 条

[1] Regulating the redox centers of Fe through the enrichment of Mo moiety for persulfate activation: A new strategy to achieve maximum persulfate utilization efficiency [J].

Ali, Jawad ;

Lei Wenli ;

Shahzad, Ajmal ;

Ifthikar, Jerosha ;

Aregay, Gebremedhin G. ;

Shahib, Irshad Ibran ;

Elkhlifi, Zouhair ;

Chen, Zhulei ;

Chen, Zhuqi .

WATER RESEARCH, 2020, 181

[2] Pathways to electrochemical solar-hydrogen technologies [J].

Ardo, Shane ;

Rivas, David Fernandez ;

Modestino, Miguel A. ;

Greiving, Verena Schulze ;

Abdi, Fatwa F. ;

Alarcon Llado, Esther ;

Artero, Vincent ;

Ayers, Katherine ;

Battaglia, Corsin ;

Becker, Jan-Philipp ;

Bederak, Dmytro ;

Berger, Alan ;

Buda, Francesco ;

Chinello, Enrico ;

Dam, Bernard ;

Di Palma, Valerio ;

Edvinsson, Tomas ;

Fujii, Katsushi ;

Gardeniers, Han ;

Geerlings, Hans ;

Hashemi, S. Mohammad H. ;

Haussener, Sophia ;

Houle, Frances ;

Huskens, Jurriaan ;

James, Brian D. ;

Konrad, Kornelia ;

Kudo, Akihiko ;

Kunturu, Pramod Patil ;

Lohse, Detlef ;

Mei, Bastian ;

Miller, Eric L. ;

Moore, Gary F. ;

Muller, Jiri ;

Orchard, Katherine L. ;

Rosser, Timothy E. ;

Saadi, Fadl H. ;

Schuttauf, Jan-Willem ;

Seger, Brian ;

Sheehan, Stafford W. ;

Smith, Wilson A. ;

Spurgeon, Joshua ;

Tang, Maureen H. ;

van de Krol, Roel ;

Vesborg, Peter C. K. ;

Westerik, Pieter .

ENERGY & ENVIRONMENTAL SCIENCE, 2018, 11 (10) :2768-2783

[3] AMORPHOUS MOLYBDENUM SULFIDE ELECTRODES FOR NONAQUEOUS ELECTROCHEMICAL-CELLS [J].

AUBORN, JJ ;

BARBERIO, YL ;

HANSON, KJ ;

SCHLEICH, DM ;

MARTIN, MJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (03) :580-586

[4]

Bag S, 2009, NAT CHEM, V1, P217, DOI [10.1038/nchem.208, 10.1038/NCHEM.208]

[5] [Mo3S13]2- as a Model System for Hydrogen Evolution Catalysis by MoSx: Probing Protonation Sites in the Gas Phase by Infrared Multiple Photon Dissociation Spectroscopy [J].

Baloglou, Aristeidis ;

Plattner, Manuel ;

Oncak, Milan ;

Grutza, Marie-Luise ;

Kurz, Philipp ;

Beyer, Martin K. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (10) :5074-5077

[6] Atomic-Scale in Situ Observations of Crystallization and Restructuring Processes in Two-Dimensional MoS2 Films [J].

Bayer, Bernhard C. ;

Kaindl, Reinhard ;

Monazam, Mohammad Reza Ahmadpour ;

Susi, Toma ;

Kotakoski, Jani ;

Gupta, Tushar ;

Eder, Dominik ;

Waldhauser, Wolfgang ;

Meyer, Jannik C. .

ACS NANO, 2018, 12 (08) :8758-8769

[7] THE ELECTRODEPOSITION OF AMORPHOUS MOLYBDENUM SULFIDE [J].

BELANGER, D ;

LAPERRIERE, G ;

MARSAN, B .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 347 (1-2) :165-183

[8] Catalyzing the Hydrogen Evolution Reaction (HER) with Molybdenum Sulfide Nanomaterials [J].

Benck, Jesse D. ;

Hellstern, Thomas R. ;

Kibsgaard, Jakob ;

Chakthranont, Pongkarn ;

Jaramillo, Thomas F. .

ACS CATALYSIS, 2014, 4 (11) :3957-3971

[9] Amorphous Molybdenum Sulfide Catalysts for Electrochemical Hydrogen Production: Insights into the Origin of their Catalytic Activity [J].

Benck, Jesse D. ;

Chen, Zhebo ;

Kuritzky, Leah Y. ;

Forman, Arnold J. ;

Jaramillo, Thomas F. .

ACS CATALYSIS, 2012, 2 (09) :1916-1923

[10] OPTICAL STUDY OF AMORPHOUS MOS3 - DETERMINATION OF THE FUNDAMENTAL ENERGY-GAP [J].

BHATTACHARYA, RN ;

LEE, CY ;

POLLAK, FH ;

SCHLEICH, DM .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1987, 91 (02) :235-242

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