Electronic communication in a novel five-step redox system

被引：24
作者：
Ding, L
Ma, KB
de Biani, FF
Bolte, M
Zanello, P
Wagner, M
机构：
[1] JW Goethe Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany
[2] Univ Siena, Dipartimento Chim, I-53100 Siena, Italy
[3] Univ Frankfurt, Inst Organ Chem, D-60439 Frankfurt, Germany
来源：
ORGANOMETALLICS | 2001年 / 20卷 / 06期
关键词：
D O I：
10.1021/om000969w
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The ansa-ferrocene complex [1,1'-fc(Bbipy)(2)O]-(PF6)(2) {[5](PF6)(2); fc = (n(5)-C5H4)(2)Fe} has been synthesized and structurally characterized. Electronic communication between the true 2,2'-bipyridylboronium substituents was observed suggesting the reduced forms [5](+) and [5](-) to be partially delocalized redox intermediates.
引用
收藏
页码：1041 / 1043
页数：3
相关论文
共 17 条
[1]   From organotransition-metal chemistry toward molecular electronics: Electronic communication between ligand-bridged metals [J].
Astruc, D .
ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (09) :383-391
[2]   Luminescent and redox-active polynuclear transition metal complexes [J].
Balzani, V ;
Juris, A ;
Venturi, M ;
Campagna, S ;
Serroni, S .
CHEMICAL REVIEWS, 1996, 96 (02) :759-833
[3]  
de Biani FF, 1997, ORGANOMETALLICS, V16, P4776
[4]  
Dinnebier RE, 2000, Z ANORG ALLG CHEM, V626, P1400, DOI 10.1002/(SICI)1521-3749(200006)626:6<1400::AID-ZAAC1400>3.0.CO
[5]  
2-8
[6]  
Fontani M, 1998, EUR J INORG CHEM, P1453
[7]  
Fontani M, 1998, EUR J INORG CHEM, P2087
[8]   Carbon-carbon bonds functioning as electron shuttles: The generation of electron-rich manganese(II) Schiff base complexes and their redox chemistry [J].
Gallo, E ;
Solari, E ;
Re, N ;
Floriani, C ;
ChiesiVilla, A ;
Rizzoli, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (22) :5144-5154
[9]  
GAN KS, 1995, FERROCENES, P41
[10]   Boron-nitrogen coordination polymers bearing ferrocene in the main chain [J].
Grosche, M ;
Herdtweck, E ;
Peters, F ;
Wagner, M .
ORGANOMETALLICS, 1999, 18 (22) :4669-4672
12