Ca(ii), Yb(ii) and Tm(iii) complexes with tri- and tetra-anions of 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene

被引：11

作者：

Fedushkin, Igor L. ^{[1
]}

Lukina, Daria A. ^{[1
]}

Skatova, Alexandra A. ^{[1
]}

Lukoyanov, Anton N. ^{[1
]}

Cherkasov, Anton V. ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Tropinina Str 49, Nizhnii Novgorod 603950, Russia

来源：

CHEMICAL COMMUNICATIONS | 2018年 / 54卷 / 92期

关键词：

NAPHTHALENE COMPLEX; MOLECULAR-STRUCTURE; LITHIUM CATIONS; LIGAND; DIANION; CRYSTAL; METAL;

D O I：

10.1039/c8cc08108e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of [(dpp-bian)M-2-(2+)(thf)(4)] (M = Ca, 1; Yb, 6; dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) by alkali metals results in heterometallic, [(dpp-bian)3-M2+K+(thf)(2)](2) (M = Ca, 2; Yb, 7), [(dpp-bian)(4-)Ca(2+)A(2)(+)(thf)(4)](2) (A = Na, 3; Li, 4; K, 5), [(dpp-bian)4-Yb2+K2+(thf)(4)](2) (8) and [(dpp-bian)(2)4-Yb32+K2+(thf)(8)] (9). The reduction of [(dpp-bian)TmBr(thf)(n)] (in situ) affords [(dpp-bian)4-Tm3+Na+(thf)](2) (10).

引用

页码：12950 / 12953

页数：4

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