Amides as Weak Coordinating Groups in Proximal C-H Bond Activation

被引：113

作者：

Das, Riki ^{[1
]}

Kumar, Gangam Srikanth ^{[1
]}

Kapur, Manmohan ^{[1
]}

机构：

[1] Indian Inst Sci Educ & Res Bhopal, Dept Chem, Bhopal Bypass Rd, Bhopal 462066, MP, India

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 2017卷 / 37期

关键词：

Transition metals; C-H activation; Weak coordinating groups; Site selectivity; Amides; Regioselectivity; CATALYZED ORTHO-ARYLATION; CROSS-COUPLING REACTION; DIRECTING-GROUP STRATEGY; N-METHOXYBENZAMIDES; ORTHO-ACYLATION; BORONIC ACIDS; OXIDATIVE OLEFINATION; DECARBOXYLATIVE ACYLATION; INTRAMOLECULAR ANNULATION; PYRROLE SYNTHESIS;

D O I：

10.1002/ejoc.201700546

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Site selectivity is an inherent challenge in C-H functionalization reactions. The most intensively sought-after approaches have involved the employment of Lewis-basic coordinating groups to direct a metal to a proximal site, in the process generating a metallacycle capable of further organometallic reactivity. In the recent years considerable effort has been directed towards the development of new transformations involving transition-metal-mediated C-H functionalization directed by weakly coordinating groups. This microreview focuses on the role and utility of amides and anilides in directed, proximal C-H bond functionalization reactions.

引用

页码：5439 / 5459

页数：21

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