A UV-LED excited photoinitiator with low toxicity and low migration for photocurable inks

被引：26

作者：

Ren, Xiaozhen ^{[1
]}

Liu, Wenkai ^{[1
]}

Yao, Qichao ^{[1
]}

Wang, Siqi ^{[1
]}

Liu, Weijian ^{[1
]}

Gu, Hua ^{[1
]}

Wang, Dongping ^{[1
,2
]}

Fan, Jiangli ^{[1
,2
]}

Peng, Xiaojun ^{[1
]}

机构：

[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China

[2] Dalian Univ Technol, Ningbo Inst, Ningbo 315016, Peoples R China

来源：

DYES AND PIGMENTS | 2022年 / 200卷

基金：

中国国家自然科学基金;

关键词：

Photoinitiator; Photocurable inks; Low-toxicity; Low-migration; Naphthimide derivatives; POLYMERIC PHOTOINITIATOR; NAPHTHALIMIDE; PHOTOPOLYMERIZATION; DYES;

D O I：

10.1016/j.dyepig.2022.110133

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

With the improvement of public's environmental protection awareness, the market share of LED in the photo curing field is also expanding rapidly, so it is necessary to develop matching photoinitiators. Here, we prepared a molecule (ND-1) possessing both co-initiating and polymerizable groups, and it exhibits a good initiation effect on acrylate monomers under UV-LED irradiation. The double bond conversion rate reaches up to 80% especially for tripropylene glycol diacrylate (TPGDA). Due to excellent photocuring effect of ND-1, it can initiate monomer polymerization in the presence of color paste and was successfully applied to photocurable inks. In addition, ND 1 exhibits low migration and low toxicity, which is very important to promote the application of packaging with photocurable inks in the food, medical, personal care and tobacco fields. Finally, the photoinitiation mechanism of ND-1 was explored. The free radicals not only come from the cleavage of CO bond, but also intermolecular hydrogen abstraction.

引用

页数：8

共 29 条

[21] A multifunctionalized macromolecular silicone-naphthalimide visible photoinitiator for free radical polymerization [J].

Yang, Jianjing ;

Liao, Wen ;

Xiong, Ying ;

Wang, Xiaoling ;

Li, Zhen ;

Tang, Hongding .

PROGRESS IN ORGANIC COATINGS, 2018, 115 :151-158

[22] Naphthalimide dyes: Polymerizable one-component visible light initiators [J].

Yang, Jianjing ;

Liao, Wen ;

Xiong, Ying ;

Wu, Qingqing ;

Wang, Xiaoling ;

Li, Zhen ;

Tang, Hongding .

DYES AND PIGMENTS, 2018, 148 :16-24

[23] Naphthalimide Aryl Sulfide Derivative Norrish Type I Photoinitiators with Excellent Stability to Sunlight under Near-UV LED [J].

Yu, Jia ;

Gao, Yanjing ;

Jiang, Shengling ;

Sun, Fang .

MACROMOLECULES, 2019, 52 (04) :1707-1717

[24] Structure Design of Naphthalimide Derivatives: Toward Versatile Photoinitiators for Near-UVNisible LEDs, 3D Printing, and Water-Soluble Photoinitiating Systems [J].

Zhang, Jing ;

Dumur, Frederic ;

Xiao, Pu ;

Graff, Bernadette ;

Bardelang, David ;

Gigmes, Didier ;

Fouassier, Jean Pierre ;

Lalevee, Jacques .

MACROMOLECULES, 2015, 48 (07) :2054-2063

[25] Photo-Induced Intermolecular Electron Transfer-Effect of Acceptor Molecular Structures [J].

Zhang, Wei ;

Liu, Xiao-song ;

Yan, Lin ;

Zhu, Gang-bei ;

Wang, Zan-hao ;

Yang, Yan-qiang .

CHINESE JOURNAL OF CHEMICAL PHYSICS, 2018, 31 (06) :772-778

[26] Study on Modified Dealkaline Lignin as Visible Light Macromolecular Photoinitiator for 3D Printing [J].

Zhang, Xueqin ;

Keck, Sarah ;

Qi, Yujie ;

Baudis, Stefan ;

Zhao, Yuxia .

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (29) :10959-10970

[27] 3D printing of multi-scalable structures via high penetration near-infrared photopolymerization [J].

Zhu, Junzhe ;

Zhang, Qiang ;

Yang, Tianqing ;

Liu, Yu ;

Liu, Ren .

NATURE COMMUNICATIONS, 2020, 11 (01)

[28] Phenacyl Phenothiazinium Salt as a New Broad-Wavelength-Absorbing Photoinitiator for Cationic and Free Radical Polymerizations [J].

Zhu, Yi ;

Xu, Dandan ;

Zhang, Yuchao ;

Zhou, Yufan ;

Yagci, Yusuf ;

Liu, Ren .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (31) :16917-16921

[29] Recent Advances and Challenges in the Design of Organic Photoacid and Photobase Generators for Polymerizations [J].

Zivic, Nicolas ;

Kuroishi, Paula K. ;

Dumur, Frederic ;

Gigmes, Didier ;

Dove, Andrew P. ;

Sardon, Haritz .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (31) :10410-10422

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