Cadmium Hydroxide: A Missing Non-Noble Metal Hydroxide Electrocatalyst for the Oxygen Evolution Reaction

被引：28
作者：
Chen, Xiang [1 ,2 ]
Wang, Haonan [3 ,4 ]
Meng, Ruru [3 ,4 ]
Xia, Bin [3 ,4 ]
Ma, Zuju [1 ,2 ]
机构：
[1] Anhui Univ Technol, Sch Mat Sci & Engn, Key Lab Met Emiss Reduct & Resources Recycling, Maanshan 243002, Peoples R China
[2] Anhui Univ Technol, Key Lab Green Fabricat & Surface Technol Adv Met, Maanshan 243002, Peoples R China
[3] Anhui Univ Technol, Key Lab Met Emiss Reduct & Resources Recycling, Maanshan 243002, Peoples R China
[4] Anhui Univ Technol, Sch Mat Sci & Engn, Maanshan 243002, Peoples R China
来源：
ACS APPLIED ENERGY MATERIALS | 2020年 / 3卷 / 02期
基金：
中国国家自然科学基金;
关键词：
cadmium hydroxide; non-noble and non-first-row transition metal; electrocatalysts; oxygen evolution reaction; excellent OER activity; CONVERSION; NANOSHEETS; CD(OH)(2); DESIGN; NI;
D O I：
10.1021/acsaem.9b02352
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An emerging non-noble-metal-based oxygen evolution reaction (OER) electrocatalyst, cadmium hydroxide (Cd(OH)(2)), has been developed in this work; this was prepared via a facile chemical precipitation method by using cadmium salt as the precursor. Without using a noble or first-row transition metal element, the as-obtained Cd(OH)(2) nanoplate electrocatalyst exhibits an impressive electrocatalytic OER performance with a low overpotential of 266 mV at the current density of 10 mA/cm(2), a low Tafel slope of 47 mV/dec, and considerable stability, results which are superior to those of noble-metal-based commercial RuO2, and comparable to those of a commonly used first-row transition-metal-based catalyst Co(OH)(2).
引用
收藏
页码：1305 / 1310
页数：11
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