Metal-mediated cleavage of unsaturated C-C bonds

被引：40

作者：

Chan, Antony P. Y. ^{[1
]}

Sergeev, Alexey G. ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Crown St, Liverpool L69 7ZD, Merseyside, England

来源：

COORDINATION CHEMISTRY REVIEWS | 2020年 / 413卷

关键词：

CARBON-CARBON BOND; CATALYZED OXIDATIVE CLEAVAGE; EQUIVALENT-TO-C; HETEROCYCLIC CARBENE LIGAND; INDEPENDENT CHEMICAL-SHIFTS; ELECTRON-RICH OLEFINS; X-RAY-STRUCTURE; TRIPLE BOND; TRANSITION-METAL; MOLECULAR-STRUCTURE;

D O I：

10.1016/j.ccr.2020.213213

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cleavage of C-C bonds by transition metal complexes is a fascinating organometallic transformation that underpins a range of industrial processes and offers exciting opportunities for development new synthetic methods through reconstruction of hydrocarbon framework. Various examples of single C-C bond cleavage have been extensively covered in recent literature, but equally rich chemistry of metal-mediated scission of unsaturated C-C bonds has not been comprehensively surveyed so far. This review aims to fill this gap and highlights stoichiometric and catalytic reactions involving metal-induced full cleavage of unsaturated C-C bonds in alkenes, alkynes and aromatic systems. (C) 2020 Elsevier B.V. All rights reserved.

引用

页数：27

共 373 条

[1] Oxo ligands as assembling units in mixed-metal cluster chemistry: Synthesis and X-ray structure of the bow-tie cluster [Mo2Ru3(mu(3)-O)(2)(mu(3)-CPh)(mu-C3Ph3)(CO)(8)(eta-C5H5)(2)] [J].

Adams, H ;

Gill, LJ ;

Morris, MJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 533 (1-2) :117-123

[2] Rearrangement and scission of terminal alkynes in dimolybdenum complexes on reaction with ruthenium carbonyl: Formation of trinuclear vinylidene and hexanuclear bis(alkylidyne) clusters [J].

Adams, H ;

Gill, LJ ;

Morris, MJ .

ORGANOMETALLICS, 1996, 15 (20) :4182-4189

[3] Dismantling a dinuclear metallacyclopentadiene: Alkyne scission in cobalt-molybdenum clusters [J].

Adams, H ;

Gill, LJ ;

Morris, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (20) :3909-3910

[4] SCISSION OF ETHYNE INTO 2 METHYLIDYNE LIGANDS - C-C VS C-H BOND ACTIVATION [J].

ADAMS, H ;

GILL, LJ ;

MORRIS, MJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (08) :899-900

[5] Alkyne scission in cobalt-molybdenum clusters: synthesis and structures of hexa- and heptanuclear alkylidyne clusters with unusual architectures [J].

Adams, H ;

Guio, LVY ;

Morris, MJ ;

Spey, SE .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (14) :2907-2915

[6] Linking and fragmentation of alkynes at a triruthenium centre [J].

Adams, KJ ;

Barker, JJ ;

Knox, SAR ;

Orpen, AG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (06) :975-988

[7] Iridium-assisted C≡C bond cleavage of 1-alkyne by water:: preparation of new alkyl derivatives [J].

Albertin, G ;

Antoniutti, S ;

Bacchi, A ;

Pelizzi, G ;

Piasente, F .

DALTON TRANSACTIONS, 2003, (14) :2881-2888

[8] Total synthesis of sperabillin A and C [J].

Allmendinger, L ;

Bauschke, G ;

Paintner, FF .

SYNLETT, 2005, (17) :2615-2618

[9] Vanadium catalyzed aerobic carbon-carbon cleavage [J].

Amadio, Emanuele ;

Di Lorenzo, Rosalia ;

Zonta, Cristiano ;

Licini, Giulia .

COORDINATION CHEMISTRY REVIEWS, 2015, 301 :147-162

[10]

[Anonymous], 2015, Cleavage of Carbon-Carbon Single Bonds by Transition Metals

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