Microfabricated microfluidic fuel cells

被引:20
作者
Kamitani, Ai [2 ]
Morishita, Satoshi [2 ]
Kotaki, Hiroshi [2 ]
Arscott, Steve [1 ]
机构
[1] Univ Lille, CNRS, IEMN, Villeneuve Dascq, France
[2] Sharp Co Ltd, Adv Technol Res Labs, Nara, Japan
关键词
Microfuel cells; Energy; Microsystems; Microfluidics; MEMS; Silicon; Fibrous materials; METHANOL CROSSOVER; FABRICATION; HYDROGEN; VOLTAGE; DESIGN; SCALE; MODEL;
D O I
10.1016/j.snb.2009.11.014
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
We demonstrate high performance microfuel cells (mu FC) operating at room temperature. The smallest mu FC has a reaction surface of 0.11 cm(2) and has an output power density equal to 22.9 mW cm(-2). Methanol and air are supplied using microchannels etched into silicon wafers using microfabrication techniques which can accurately determine the mu FC surface and the microchannel dimensions. The insertion of a novel hydrophilic fibrous layer into the anode diffusion layer stack produces 9.25 mW cm(-2) for an input fuel flow rate of 550 nL min(-1). The benefits of size-scaling and architecture optimization in mu FC are demonstrated. Our observations and conclusions are by no means unique to methanol mu FC but could be applied to other microfluidic liquid fuel mu FC based on, e.g. microbial fuel cells. bio-ethanol and glucose solution. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:174 / 180
页数:7
相关论文
共 29 条
[1]  
Aricò AS, 2001, FUEL CELLS, V1, P133
[2]   Surface micromachining for microelectromechanical systems [J].
Bustillo, JM ;
Howe, RT ;
Muller, RS .
PROCEEDINGS OF THE IEEE, 1998, 86 (08) :1552-1574
[3]   Integrated microfluidics based on multi-layered SU-8 for mass spectrometry analysis [J].
Carlier, J ;
Arscott, S ;
Thomy, V ;
Fourrier, JC ;
Caron, F ;
Camart, JC ;
Druon, C ;
Tabourier, P .
JOURNAL OF MICROMECHANICS AND MICROENGINEERING, 2004, 14 (04) :619-624
[4]   Geometric scale effect of flow channels on performance of fuel cells [J].
Cha, SW ;
O'Hayre, R ;
Lee, SJ ;
Saito, Y ;
Prinz, FB .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (11) :A1856-A1864
[5]   The current voltage plot of PEM fuel cell with long feed channels [J].
Dohle, H ;
Kornyshev, AA ;
Kulikovsky, AA ;
Mergel, J ;
Stolten, D .
ELECTROCHEMISTRY COMMUNICATIONS, 2001, 3 (02) :73-80
[6]   DMFC at low air flow operation: Study of parasitic hydrogen generation [J].
Dohle, H. ;
Mergel, J. ;
Ghosh, P. C. .
ELECTROCHIMICA ACTA, 2007, 52 (19) :6060-6067
[7]   Fabrication and characterization of a passive silicon-based direct methanol fuel cell [J].
Esquivel, J. P. ;
Sabate, N. ;
Santander, J. ;
Torres, N. ;
Cane, C. .
MICROSYSTEM TECHNOLOGIES-MICRO-AND NANOSYSTEMS-INFORMATION STORAGE AND PROCESSING SYSTEMS, 2008, 14 (4-5) :535-541
[8]   A three-dimensional mathematical model for liquid-fed direct methanol fuel cells [J].
Ge, Jiabin ;
Liu, Hongtan .
JOURNAL OF POWER SOURCES, 2006, 160 (01) :413-421
[9]   2D analytical model of a direct methanol fuel cell [J].
Guo, H ;
Ma, CF .
ELECTROCHEMISTRY COMMUNICATIONS, 2004, 6 (03) :306-312
[10]   Design, fabrication and testing of a silicon-based air-breathing micro direct methanol fuel cell [J].
Jiang, Yingqi ;
Wang, Xiaohong ;
Zhong, Lingyan ;
Liu, Litian .
JOURNAL OF MICROMECHANICS AND MICROENGINEERING, 2006, 16 (09) :S233-S239