Desulfonative pd-catalyzed coupling of aryl trifluoroborates with arylsulfonyl chlorides

被引：11

作者：

Wei, Zhen ^{[1
]}

Xue, Dazhong ^{[2
]}

Zhang, Haisheng ^{[3
]}

Guan, Jinyu ^{[1
]}

机构：

[1] Hebei North Univ, Coll Sci, Zhangjiakou 075000, Hebei, Peoples R China

[2] Hebei North Univ, Coll Basic Med, Zhangjiakou 075000, Hebei, Peoples R China

[3] First High Sch Zhangjiakou, Phys Educ Res Grp, Zhangjiakou 075000, Hebei, Peoples R China

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2016年 / 30卷 / 09期

关键词：

arylsulfonyl chlorides; Pd-catalyzed; Suzuki-Miyaura coupling; aryl trifluoroborates; MIYAURA CROSS-COUPLINGS; PALLADIUM CATALYSTS; ARENESULFONYL CHLORIDES; ARENEDIAZONIUM SALTS; ARYLBORONIC ACIDS; ORGANIC-SYNTHESIS; LIGAND-FREE; HYDRAZIDES; EFFICIENT; ALKYNES;

D O I：

10.1002/aoc.3504

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A Pd-catalyzed cross-coupling of aryl trifluoroborates with arylsulfonyl chlorides has been successfully achieved. This transformation is a new method for the Suzuki-Miyaura-type reaction of aryl trifluoroborates via the cleavage of C S bond, thus providing an alternative synthesis of biaryls. The reported cross-coupling reactions are tolerant to many common functional groups regardless of electron-donating or electron-withdrawing nature, making these transformations attractive alternatives to the traditional Suzuki-Miyaura coupling approaches. Copyright (c) 2016 John Wiley & Sons, Ltd.

引用

页码：767 / 771

页数：5

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