Desulfonative pd-catalyzed coupling of aryl trifluoroborates with arylsulfonyl chlorides

被引：11
|
作者：
Wei, Zhen [1 ]
Xue, Dazhong [2 ]
Zhang, Haisheng [3 ]
Guan, Jinyu [1 ]
机构：
[1] Hebei North Univ, Coll Sci, Zhangjiakou 075000, Hebei, Peoples R China
[2] Hebei North Univ, Coll Basic Med, Zhangjiakou 075000, Hebei, Peoples R China
[3] First High Sch Zhangjiakou, Phys Educ Res Grp, Zhangjiakou 075000, Hebei, Peoples R China
来源：
APPLIED ORGANOMETALLIC CHEMISTRY | 2016年 / 30卷 / 09期
关键词：
arylsulfonyl chlorides; Pd-catalyzed; Suzuki-Miyaura coupling; aryl trifluoroborates; MIYAURA CROSS-COUPLINGS; PALLADIUM CATALYSTS; ARENESULFONYL CHLORIDES; ARENEDIAZONIUM SALTS; ARYLBORONIC ACIDS; ORGANIC-SYNTHESIS; LIGAND-FREE; HYDRAZIDES; EFFICIENT; ALKYNES;
D O I：
10.1002/aoc.3504
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
A Pd-catalyzed cross-coupling of aryl trifluoroborates with arylsulfonyl chlorides has been successfully achieved. This transformation is a new method for the Suzuki-Miyaura-type reaction of aryl trifluoroborates via the cleavage of C S bond, thus providing an alternative synthesis of biaryls. The reported cross-coupling reactions are tolerant to many common functional groups regardless of electron-donating or electron-withdrawing nature, making these transformations attractive alternatives to the traditional Suzuki-Miyaura coupling approaches. Copyright (c) 2016 John Wiley & Sons, Ltd.
引用
收藏
页码：767 / 771
页数：5
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