Dioxypyrrole and dioxythiophene based conducting polymers: properties and applications

被引：11

作者：

Giurgiu, I

Zong, K

Reynolds, JR ^{[1
]}

Lee, WP

Brenneman, KR

Saprigin, AV

Epstein, AJ

Hwang, J

Tanner, DB

机构：

[1] Univ Florida, Ctr Macromol Sci & Engn, Dept Chem, Gainesville, FL 32611 USA

[2] Univ Florida, Ctr Macromol Sci & Engn, Dept Phys, Gainesville, FL 32611 USA

[3] Ohio State Univ, Dept Phys, Columbus, OH 43210 USA

[4] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

[5] Ohio State Univ, Chem Phys Program, Columbus, OH 43210 USA

来源：

SYNTHETIC METALS | 2001年 / 119卷 / 1-3期

关键词：

conductivity; polythiophene and derivatives; polypyrrole and derivatives; switches; transport measurements; UV-Vis-NIR;

D O I：

10.1016/S0379-6779(00)01142-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We have focused recent efforts on developing an understanding of how to optimise the electrical, spectroscopic, electrochemical and physical properties of poly(3,4-alkyenedioxythiophene) (PXDOT) and poly(3,4-alkylenedioxypyrrole) (PXDOP) based conjugated polymers. Here we present the results of the temperature dependence of the de and microwave conductivity, as well as magnetic susceptibility and reflectance data, for electrochemically synthesized, free standing, PXDOT and PXDOP films doped with different organic anions. The polymers have properties that are characteristic of disordered materials near the insulator-metal transition (IMT). We also investigate the possibility of applying these polymers as the active layer in visible and IR light emissivity control devices.

引用

页码：405 / 406

页数：2

共 11 条

[1] Electronic transport in doped poly(3,4-ethylenedioxythiophene) near the metal-insulator transition [J].