A glass formation study of aqueous tetraalkylammonium nitrate solutions

被引：5
|
作者：
Ohnishi, A
Kanno, H
机构：
[1] Department of Chemistry, National Defense Academy, Yokosuka
来源：
JOURNAL OF SOLUTION CHEMISTRY | 1996年 / 25卷 / 03期
关键词：
glass formation; aqueous solution; tetraalkylammonium nitrate; hydrophobic interaction; glass transition temperature;
D O I：
10.1007/BF00972525
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The glass-forming composition regions of aqueous tetraalkylammonium nitrate solutions (alkyl = ethyl and n-propyl) were determined by a simple DTA method with a cooling rate of about 600 K-min(-1). The glass transition temperatures T-g of these solutions vary in a different manner from those for simple inorganic salt solutions such as aqueous LiCl, MgCl2, and AlCl3 solutions. Liquid-liquid immiscibilities are observed in these solutions at low temperatures.
引用
收藏
页码：279 / 287
页数：9
相关论文
共 50 条
  • [31] A GLASS-FORMATION STUDY OF AQUEOUS RARE-EARTH ELECTROLYTE-SOLUTIONS
    KANNO, H
    AKAMA, Y
    JOURNAL OF PHYSICAL CHEMISTRY, 1987, 91 (05): : 1263 - 1266
  • [32] IR spectroscopic investigation of aqueous solutions of tetraalkylammonium salts
    Olsen, Robert J.
    Sattar, Simeen
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [33] MEDIUM EFFECTS ON TETRAALKYLAMMONIUM IONS IN AQUEOUS ACID SOLUTIONS
    MODRO, TA
    REYNOLDS, WF
    YATES, K
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1976, 54 (09): : 1439 - 1444
  • [34] ISOTHERMAL COMPRESSIBILITIES OF AQUEOUS-SOLUTIONS OF TETRAALKYLAMMONIUM BROMIDES
    DESNOYERS, JE
    PHILIP, PR
    CANADIAN JOURNAL OF CHEMISTRY-BACK YEAR, 1972, 50 (07): : 1094 - +
  • [35] Ionic association in aqueous solutions of salts with tetraalkylammonium ions
    Krumgalz, Boris S.
    1997, Elsevier (73-74)
  • [36] A Spectrophotometric Study of Nitrate and Nitrite Salts and Their Aqueous Solutions
    Aluker, N. L.
    Herrmann, M. E.
    Suzdaltseva, Ya. M.
    OPTICS AND SPECTROSCOPY, 2019, 127 (06) : 991 - 996
  • [37] LASER RAMAN STUDY OF AQUEOUS COPPER NITRATE SOLUTIONS
    DAVIS, AR
    CHONG, C
    INORGANIC CHEMISTRY, 1972, 11 (08) : 1891 - &
  • [38] A VIBRATIONAL SPECTROSCOPIC STUDY OF AQUEOUS CADMIUM NITRATE SOLUTIONS
    DAVIS, AR
    PLANE, RA
    INORGANIC CHEMISTRY, 1968, 7 (12) : 2565 - &
  • [39] A Spectrophotometric Study of Nitrate and Nitrite Salts and Their Aqueous Solutions
    N. L. Aluker
    M. E. Herrmann
    Ya. M. Suzdaltseva
    Optics and Spectroscopy, 2019, 127 : 991 - 996
  • [40] Study of Gelation in Aqueous Solutions of Cysteine and Silver Nitrate
    P. M. Pakhomov
    M. M. Ovchinnikov
    S. D. Khizhnyak
    M. V. Lavrienko
    W. Nierling
    M. D. Lechner
    Colloid Journal, 2004, 66 : 65 - 70
12345