Tailored HoFeO3-Ho2O3 hybrid perovskite nanocomposites as stable anode material for advanced lithium-ion storage

被引:13
作者
Anh Tien Nguyen [1 ]
Kidanu, Weldejewergis Gebrewahid [2 ,3 ]
Mittova, Valentina Olegovna [4 ]
Van Hoang Nguyen [5 ,6 ,7 ]
Dinh Quan Nguyen [7 ,8 ]
My Loan Phung Le [5 ,6 ,7 ]
Mittova, Irina Yakovlevna [9 ]
Il Tae Kim [2 ]
Tuan Loi Nguyen [10 ,11 ]
机构
[1] Ho Chi Minh City Univ Educ, Fac Chem, Ho Chi Minh City, Vietnam
[2] Gachon Univ, Dept Chem & Biol Engn, Seongnam Si 13120, Gyeonggi Do, South Korea
[3] Mekelle Univ, Ethiopian Inst Technol Mekelle EIT M, Dept Chem Engn, Mekelle, Ethiopia
[4] Voronezh State Med Univ, Dept Biochem, Voronezh, Russia
[5] VNUHCM Univ Sci, Fac Chem, Dept Phys Chem, Ho Chi Minh City, Vietnam
[6] VNUHCM Univ Sci, Fac Chem, Appl Phys Chem Lab APCLAB, Ho Chi Minh City, Vietnam
[7] Vietnam Natl Univ Ho Chi Minh City VNUHCM, Ho Chi Minh City, Vietnam
[8] Ho Chi Minh City Univ Technol HCMUT, Fac Chem Engn, Lab Biofuel & Biomass Res, Ho Chi Minh City, Vietnam
[9] Voronezh State Univ, Fac Chem, Voronezh, Russia
[10] Duy Tan Univ, Inst Fundamental & Appl Sci, Ho Chi Minh City 700000, Vietnam
[11] Duy Tan Univ, Fac Environm & Chem Engn, Da Nang City, Vietnam
关键词
anode; HoFeO3-Ho2O3; nanocomposite; lithium-ion battery; perovskite; porous nanohallow structure; ELECTRODE MATERIALS; FACILE SYNTHESIS; THIN-FILMS; COMPOSITE; BATTERIES; SODIUM; TEMPERATURE; CAPABILITY; CHALLENGES; MICROSCOPY;
D O I
10.1002/er.7273
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this study, a novel hybrid HoFeO3-Ho2O3 nanocomposite perovskite composite is synthesized via a simple coprecipitation method as a stable, high-capacity anode material for lithium-ion batteries. The structure and morphology of the material are characterized using advanced tools such as X-ray diffraction, scanning electron microscopy, and transmission electron microscopy, all of which confirm the successful synthesis of nanocrystals with highly interconnected porous nanohallows. At 0.1 A g(-1), the HoFeO3-Ho2O3 nanocomposite electrodes exhibit a stable reversible capacity of 787 mAh g(-1) with a coulombic efficiency exceeding 99.5%. This capacity is nine times higher than that of Ho2O3 and 50% higher than that of Fe2O3 balance samples. This study provides new insights into the use of perovskite-structured materials with superior electrochemical performance for advanced lithium-ion storage.
引用
收藏
页码:2051 / 2063
页数:13
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