Tailored HoFeO3-Ho2O3 hybrid perovskite nanocomposites as stable anode material for advanced lithium-ion storage

被引:13
作者
Anh Tien Nguyen [1 ]
Kidanu, Weldejewergis Gebrewahid [2 ,3 ]
Mittova, Valentina Olegovna [4 ]
Van Hoang Nguyen [5 ,6 ,7 ]
Dinh Quan Nguyen [7 ,8 ]
My Loan Phung Le [5 ,6 ,7 ]
Mittova, Irina Yakovlevna [9 ]
Il Tae Kim [2 ]
Tuan Loi Nguyen [10 ,11 ]
机构
[1] Ho Chi Minh City Univ Educ, Fac Chem, Ho Chi Minh City, Vietnam
[2] Gachon Univ, Dept Chem & Biol Engn, Seongnam Si 13120, Gyeonggi Do, South Korea
[3] Mekelle Univ, Ethiopian Inst Technol Mekelle EIT M, Dept Chem Engn, Mekelle, Ethiopia
[4] Voronezh State Med Univ, Dept Biochem, Voronezh, Russia
[5] VNUHCM Univ Sci, Fac Chem, Dept Phys Chem, Ho Chi Minh City, Vietnam
[6] VNUHCM Univ Sci, Fac Chem, Appl Phys Chem Lab APCLAB, Ho Chi Minh City, Vietnam
[7] Vietnam Natl Univ Ho Chi Minh City VNUHCM, Ho Chi Minh City, Vietnam
[8] Ho Chi Minh City Univ Technol HCMUT, Fac Chem Engn, Lab Biofuel & Biomass Res, Ho Chi Minh City, Vietnam
[9] Voronezh State Univ, Fac Chem, Voronezh, Russia
[10] Duy Tan Univ, Inst Fundamental & Appl Sci, Ho Chi Minh City 700000, Vietnam
[11] Duy Tan Univ, Fac Environm & Chem Engn, Da Nang City, Vietnam
关键词
anode; HoFeO3-Ho2O3; nanocomposite; lithium-ion battery; perovskite; porous nanohallow structure; ELECTRODE MATERIALS; FACILE SYNTHESIS; THIN-FILMS; COMPOSITE; BATTERIES; SODIUM; TEMPERATURE; CAPABILITY; CHALLENGES; MICROSCOPY;
D O I
10.1002/er.7273
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this study, a novel hybrid HoFeO3-Ho2O3 nanocomposite perovskite composite is synthesized via a simple coprecipitation method as a stable, high-capacity anode material for lithium-ion batteries. The structure and morphology of the material are characterized using advanced tools such as X-ray diffraction, scanning electron microscopy, and transmission electron microscopy, all of which confirm the successful synthesis of nanocrystals with highly interconnected porous nanohallows. At 0.1 A g(-1), the HoFeO3-Ho2O3 nanocomposite electrodes exhibit a stable reversible capacity of 787 mAh g(-1) with a coulombic efficiency exceeding 99.5%. This capacity is nine times higher than that of Ho2O3 and 50% higher than that of Fe2O3 balance samples. This study provides new insights into the use of perovskite-structured materials with superior electrochemical performance for advanced lithium-ion storage.
引用
收藏
页码:2051 / 2063
页数:13
相关论文
共 47 条
[1]   Electrochemical Impedance Spectroscopy on the Performance Degradation of LiFePO4/Graphite Lithium-Ion Battery Due to Charge-Discharge Cycling under Different C-Rates [J].
Abe, Yusuke ;
Hori, Natsuki ;
Kumagai, Seiji .
ENERGIES, 2019, 12 (23)
[2]   Antimony alloying electrode for high-performance sodium removal: how to use a battery material not stable in aqueous media for saline water remediation [J].
Arnold, Stefanie ;
Wang, Lei ;
Budak, Oeznil ;
Aslan, Mesut ;
Srimuk, Pattarachai ;
Presser, Volker .
JOURNAL OF MATERIALS CHEMISTRY A, 2021, 9 (01) :585-596
[3]   Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions [J].
Cabana, Jordi ;
Monconduit, Laure ;
Larcher, Dominique ;
Rosa Palacin, M. .
ADVANCED MATERIALS, 2010, 22 (35) :E170-E192
[4]   Highly compressible zinc-ion batteries with stable performance [J].
Cao, Hongmei ;
Wan, Fang ;
Zhang, Linlin ;
Dai, Xi ;
Huang, Shuo ;
Liu, Lili ;
Niu, Zhiqiang .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (19) :11734-11741
[5]   Building a Better Battery [J].
Chiang, Yet-Ming .
SCIENCE, 2010, 330 (6010) :1485-1486
[6]  
Débart A, 2001, J ELECTROCHEM SOC, V148, pA1266, DOI 10.1149/1.1409971
[7]   Perovskite oxides for semiconductor-based gas sensors [J].
Fergus, Jeffrey W. .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 123 (02) :1169-1179
[8]   Design, synthesis and lithium-ion storage capability of Al0.5Nb24.5O62 [J].
Fu, Qingfeng ;
Li, Renjie ;
Zhu, Xiangzhen ;
Liang, Guisheng ;
Luo, Lijie ;
Chen, Yongjun ;
Lin, Chunfu ;
Zhao, X. S. .
JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (34) :19862-19871
[9]   Review of electrical energy storage technologies, materials and systems: challenges and prospects for large-scale grid storage [J].
Gur, Turgut M. .
ENERGY & ENVIRONMENTAL SCIENCE, 2018, 11 (10) :2696-2767
[10]   Facile syntheses of perovskite type LaMO3 (M=Fe, Co, Ni) nanofibers for high performance supercapacitor electrodes and lithium-ion battery anodes [J].
Hu, Quanli ;
Yue, Bin ;
Shao, Hongyang ;
Yang, Fan ;
Wang, Jinghui ;
Wang, Yin ;
Liu, Jinghai .
JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 852