The use of soluble polymers to effect homogeneous catalyst separation and reuse

被引：86

作者：

Bergbreiter, DE ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

CATALYSIS TODAY | 1998年 / 42卷 / 04期

基金：

美国国家科学基金会;

关键词：

green chemistry; recycling; polymer support; homogenous catalysis; separation;

D O I：

10.1016/S0920-5861(98)00121-7

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The use of soluble polymeric ligands for homogeneous catalysts separation is reviewed with emphasis on work from the author's laboratory. Examples discussed include polyethylene-bound catalysts, poly(alkene oxide)-bound catalysts, poly(N-isopropylacrylamide)-bound catalysts, fluorous polymer-bound catalysts and amphoteric polymer-bound catalysts. The utility of these systems is also discussed in the broader context of polymer-supported catalysis and the advantages and limitations of soluble polymeric ligands are discussed in this context. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：389 / 397

页数：9

共 44 条

[31] WATER-SOLUBLE LIGANDS, METAL-COMPLEXES, AND CATALYSTS - SYNERGISM OF HOMOGENEOUS AND HETEROGENEOUS CATALYSIS [J].

HERRMANN, WA ;

KOHLPAINTNER, CW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (11) :1524-1544

[32] FACILE CATALYST SEPARATION WITHOUT WATER - FLUOROUS BIPHASE HYDROFORMYLATION OF OLEFINS [J].

HORVATH, IT ;

RABAI, J .

SCIENCE, 1994, 266 (5182) :72-75

[33] Thermoregulated phase transfer ligands and catalysis .1. Synthesis of novel polyether-substituted triphenylphosphines and application of their rhodium complexes in two-phase hydroformylation [J].

Jin, ZL ;

Zheng, XL ;

Fell, B .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 116 (1-2) :55-58

[34] Transition metal catalysis in fluorous media: Practical application of a new immobilization principle to rhodium-catalyzed hydroboration [J].

Juliette, JJJ ;

Horvath, IT ;

Gladysz, JA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (15) :1610-1612

[35] Macrocomplexes on the basis of functionalized polyethylene glycols and copolymers of ethylene oxide and propylene oxide: Synthesis and catalysis [J].

Karakhanov, EA ;

Kardasheva, YS ;

Maksimov, AL ;

Predeina, VV ;

Runova, EA ;

Utukin, AM .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 107 (1-3) :235-240

[36]

MARIAGNANAM VM, 1995, THESIS TEXAS A M U

[37]

Mathur N., 1980, POLYM AIDS ORGANIC C

[38] Design of nonionic surfactants for supercritical carbon dioxide [J].

McClain, JB ;

Betts, DE ;

Canelas, DA ;

Samulski, ET ;

DeSimone, JM ;

Londono, JD ;

Cochran, HD ;

Wignall, GD ;

ChilluraMartino, D ;

Triolo, R .

SCIENCE, 1996, 274 (5295) :2049-2052

[39] Infrared thermographic screening of combinatorial libraries of heterogeneous catalysts [J].

Moates, FC ;

Somani, M ;

Annamalai, J ;

Richardson, JT ;

Luss, D ;

Willson, RC .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1996, 35 (12) :4801-4803

[40] SYNTHESIS OF FUNCTIONAL CHELATING DIPHOSPHINES CONTAINING THE BIS[2-(DIPHENYLPHOSPHINO)ETHYL]AMINO MOIETY AND THE USE OF THESE MATERIALS IN THE PREPARATION OF WATER-SOLUBLE DIPHOSPHINE COMPLEXES OF TRANSITION-METALS [J].

NUZZO, RG ;

HAYNIE, SL ;

WILSON, ME ;

WHITESIDES, GM .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (14) :2861-2867

← 1 2 3 4 5 →