Carbon microbeads produced through synthesis and pyrolysis of poly(1,8-dibutyl-1,3,5,7-octatetrayne)

被引：24

作者：

Ding, LH ^{[1
]}

Olesik, SV ^{[1
]}

机构：

[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA

来源：

CHEMISTRY OF MATERIALS | 2005年 / 17卷 / 09期

关键词：

D O I：

10.1021/cm048781g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A self-polymerizable liquid octatetrayne, 1,8-dibutyl-1,3,5,7-octatetrayne, was heated to 80 degrees C and produced cross-linked poly(1,8-dibutyl-1,3,5,7-octatetrayne) microbeads via suspension polymerization with diameters adjustable from hundreds of micrometers to a few micrometers. Carbon microbeads that may be useful for catalyst supports or in high-performance carbon materials were obtained by the pyrolysis of poly(1,8-dibutyl- 1,3,5,7-octatetrayne) microbeads at 800 degrees C under an inert atmosphere.

引用

页码：2353 / 2360

页数：8

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