Red and Blue Compounds Formed from Copper(II) Bromide and the Ligand 7-Isobutyl-5-methyl-[1,2,4]triazolo [1,5-a]pyrimidine: Synthesis, Spectroscopy and Single-Crystal Structures

被引：0

作者：

Gunay, Esref ^{[1
]}

Mutikainen, Ilpo ^{[2
]}

Turpeinen, Urho ^{[2
]}

van Albada, Gerard A. ^{[1
]}

Haasnoot, Jaap G. ^{[1
]}

Reedijk, Jan ^{[1
]}

机构：

[1] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

[2] Univ Helsinki, Dept Chem, Inorgan Chem Lab, Helsinki 00014, Finland

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2010年 / 40卷 / 11期

关键词：

Copper; Bromide; Triazolopyrimidine; X-RAY-STRUCTURE; PLATINUM(II) COMPLEXES; MAGNETIC-PROPERTIES; COORDINATION CHEMISTRY; MOLECULAR-STRUCTURE; METAL-COMPLEXES; DERIVATIVES; COBALT(II); SPECTRA;

D O I：

10.1007/s10870.010.9785.8

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Two newly synthesized coordination compounds copper(II) bromide with the ligand 7-isobutyl-5-methyl[1,2,4]triazolo[1,5-a]pyrimidine (abbreviated as ibmtp) are presented, together with their 3D crystal structure and spectroscopic and magnetic properties The compounds are CuBr2(ibmtp)(2) (1) (red crystals) and [CuBr(ibmtp)(4)] Br(H2O)(3) (2) (blue crystals) In (1) the Cu(II) ion is present in a distorted tetrahedral environment, while in (2) the Cu(II) ion has a square pyramidal geometry These crystal structures are also the first ones reported with the ligand ibmtp

引用

页码：1006 / 1010

页数：5

共 31 条

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